中国塑料 ›› 2010, Vol. 24 ›› Issue (11): 26-30 .DOI: 10.19491/j.issn.1001-9278.2010.11.006

• 材料与性能 • 上一篇    下一篇

大豆分离蛋白的化学改性和增塑研究

胡世明 崔永岩 杨振兴 赵振伦   

  1. 天津科技大学 天津科技大学
  • 收稿日期:2010-07-06 修回日期:1900-01-01 出版日期:2010-11-26 发布日期:2010-11-26

Study on Chemical Modification and Plasticization of Soy Protein Isolate

HU shi ming yongyan cui   

  • Received:2010-07-06 Revised:1900-01-01 Online:2010-11-26 Published:2010-11-26
  • Contact: HU shi ming

摘要: 研究了尿素、氢氧化钠和二甲基二氯硅烷对大豆分离蛋白的化学改性以及甘油、聚乙二醇、山梨醇、己内酰胺、乙酰胺对改性蛋白质材料的增塑作用。采用红外光谱对改性蛋白质进行了表征,并测试了改性蛋白质的热性能、力学性能、流变性能及耐水性能。结果表明,强碱可以有效地截断蛋白质分子的长链结构,提高蛋白质分子的加工流动性;尿素和二甲基二氯硅烷与蛋白质分子中的亲水基团发生反应或遮盖了蛋白质分子中的亲水基团,从而提高了大豆分离蛋白的耐水性;聚乙二醇和己内酰胺是效果较好的增塑剂。

关键词: 大豆分离蛋白, 化学改性, 长链结构, 增塑, 加工流动性

Abstract: The chemical modification of soybean protein with urea, sodium hydroxide, and methy1dichlorosi1ane and the plasticization of the modified soy protein isolate using glycerol, polyethylene glycol, sorbitol, caprolactam, and ethyl amide. The structure of modified soy protein isolate was characterized,and the thermal, mechanical, and rheological properties as well as water resistance of the modified soy protein isolate were studied. The long chain of protein could be cut effectively by alkali which increased the processability of protein. The hydrophilic group in the protein molecules could be reacted off or covered by urea and dimethyldichlorosilane, so the water resistance of the materials was increased. Polyethylene glycol and caprolactam were proven effective plasticizers.

Key words: soy protein isolate, chemical modification, long chain, plastication, flow ability