聚酯类增塑剂的合成与应用研究进展

doi:10.19491/j.issn.1001-9278.2020.07.018

中国塑料 ›› 2020, Vol. 34 ›› Issue (7): 109-117.DOI: 10.19491/j.issn.1001-9278.2020.07.018

• 综述 • 上一篇

聚酯类增塑剂的合成与应用研究进展

李金禹¹, 戴亚杰¹, 陈宇²(), 孙同兵²

^1.哈尔滨理工大学，哈尔滨 150040
^2.北京华腾新材料股份有限公司，北京 100084

收稿日期:2020-02-26 出版日期:2020-07-26 发布日期:2020-07-26

Progress in Synthesis and Applications of Polyester Plasticizers

Jinyu LI¹, Yajie DAI¹, Yu CHEN²(), Tongbing SUN²

^1.Harbin University of Science and Technology, Harbin 150040，China
^2.Beijing Huateng New Materials Co, Ltd, Beijing 100084，China

Received:2020-02-26 Online:2020-07-26 Published:2020-07-26
Contact: Yu CHEN E-mail:chenyu6911@163.com

摘要/Abstract

摘要：

综述了国内外聚酯增塑剂的合成及应用的最新研究进展，重点介绍了超支化、生物基、石油基聚酯增塑剂的合成与制备方法以及不同类型聚酯增塑剂在聚氯乙烯(PVC)、淀粉、聚乳酸、聚氨酯弹性体与橡胶制品中的最新应用研究进展；并对聚酯增塑剂未来发展方向做了展望。

关键词: 聚酯多元醇, 增塑剂, 聚氯乙烯, 聚氨酯, 橡胶

Abstract:

This paper reviewed the latest research progress in synthesis and applications of polyester plasticizers at home and abroad, which mainly focused on the synthesis and preparation methods of hyperbranched, bio?based, and petroleum?based polyester plasticizers. The paper also introduced the latest research progress in the applications of the different types of polyester plasticizers for poly(vinyl chloride), starch, polylactic acid, polyurethane elastomers and rubber products. Finally, the development direction of polyester plasticizers in future was prospected.

Key words: polyester polyol, plasticizer, poly(vinyl chloride), polyurethane, rubber

中图分类号:

TQ 323.4

李金禹, 戴亚杰, 陈宇, 孙同兵. 聚酯类增塑剂的合成与应用研究进展[J]. 中国塑料, 2020, 34(7): 109-117.

Jinyu LI, Yajie DAI, Yu CHEN, Tongbing SUN. Progress in Synthesis and Applications of Polyester Plasticizers[J]. China Plastics, 2020, 34(7): 109-117.

图/表 6

参考文献 51

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聚酯增塑剂种类	聚酯增塑剂	应用范围	参考文献
超支化聚酯	超支化聚酯增塑剂P500	PVC	[19]
	聚酯?b?(ε?己内酯)超支化聚酯增塑剂		[20]
	芳香族超支化聚酯(HBPE)		[21]
	TMP改性聚己二酸丙二醇酯		[22]
	聚柠檬酸甘油酯	淀粉	[23]
	超支化聚酯多元醇(HBPS)	淀粉	[24]
	超支化聚酯(HBP)	聚乳酸	[25]
生物基聚酯	聚戊二酸?甘油单油酸酯(PGAGMO)	PVC	[26]
	基于棕榈油单甘油酯聚酯增塑剂(POMP)		[27]
	聚丁烯?2?甲基琥珀酸酯		[28]
	聚二元酸异山梨醇酯		[29]
	棕榈油改性聚酯		[2]
	聚羟基烷酸酯		[9]
	苹果酸系列聚酯多元醇	聚氨酯	[30]
	聚己二酸1,4?丁二醇酯		[31]
	耐热芳香族聚酯多元醇		[39]
	聚琥珀酸丙二醇酯		[35]
	结晶性和无定形聚壬二酸酯		[37]
	棕榈油基聚酯多元醇		[38]
	生物甘油基聚酯	大豆分离蛋白膜	[32]
石油基聚酯	聚1,5?戊二醇二苯甲酸酯	PVC	[1]
	脂肪族共聚酯		[44]
	聚丁二酸1,6?己二醇酯(PHS)		[45]
	纳迪克酸酐聚酯		[46]
	PET与EG糖酵解中间产物聚酯		[47]
	含羟甲基氧化磷基团聚己二酸丁二醇酯(BPBAP)		[48]
	硅氢化改性聚马来酸己二醇酯(MHA)		[49]
	聚酯/DOP复配体系	丁腈橡胶	[51]
	聚己二酸二辛酯	丁腈橡胶	[12]

聚酯增塑剂种类	聚酯增塑剂	应用范围	参考文献
超支化聚酯	超支化聚酯增塑剂P500	PVC	[19]
	聚酯?b?(ε?己内酯)超支化聚酯增塑剂		[20]
	芳香族超支化聚酯(HBPE)		[21]
	TMP改性聚己二酸丙二醇酯		[22]
	聚柠檬酸甘油酯	淀粉	[23]
	超支化聚酯多元醇(HBPS)	淀粉	[24]
	超支化聚酯(HBP)	聚乳酸	[25]
生物基聚酯	聚戊二酸?甘油单油酸酯(PGAGMO)	PVC	[26]
	基于棕榈油单甘油酯聚酯增塑剂(POMP)		[27]
	聚丁烯?2?甲基琥珀酸酯		[28]
	聚二元酸异山梨醇酯		[29]
	棕榈油改性聚酯		[2]
	聚羟基烷酸酯		[9]
	苹果酸系列聚酯多元醇	聚氨酯	[30]
	聚己二酸1,4?丁二醇酯		[31]
	耐热芳香族聚酯多元醇		[39]
	聚琥珀酸丙二醇酯		[35]
	结晶性和无定形聚壬二酸酯		[37]
	棕榈油基聚酯多元醇		[38]
	生物甘油基聚酯	大豆分离蛋白膜	[32]
石油基聚酯	聚1,5?戊二醇二苯甲酸酯	PVC	[1]
	脂肪族共聚酯		[44]
	聚丁二酸1,6?己二醇酯(PHS)		[45]
	纳迪克酸酐聚酯		[46]
	PET与EG糖酵解中间产物聚酯		[47]
	含羟甲基氧化磷基团聚己二酸丁二醇酯(BPBAP)		[48]
	硅氢化改性聚马来酸己二醇酯(MHA)		[49]
	聚酯/DOP复配体系	丁腈橡胶	[51]
	聚己二酸二辛酯	丁腈橡胶	[12]

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聚酯类增塑剂的合成与应用研究进展

Progress in Synthesis and Applications of Polyester Plasticizers

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