中国塑料 ›› 2014, Vol. 28 ›› Issue (09): 46-51.DOI: 10.19491/j.issn.1001-9278.2014.09.009

• 材料与性能 • 上一篇    下一篇

亚微米级β-SiC晶须改性三元BMI树脂体系的研究

  

  • 收稿日期:2014-03-14 修回日期:2014-05-23 出版日期:2014-09-26 发布日期:2014-09-26
  • 基金资助:

Study on Ternary-BMI Resin System Modified by Submicron β-SiC Whisker

  • Received:2014-03-14 Revised:2014-05-23 Online:2014-09-26 Published:2014-09-26

摘要: 将亚微米级碳化硅(β-SiC)晶须使用硅烷偶联剂进行表面处理,用处理的β-SiC晶须改性实验室制备的一种韧性三元双马来酰亚胺树脂体系(BDM/BPA-BMI/DABPA)。研究了β-SiC晶须用量对BDM/BMPP/DABPA三元体系性能的影响。结果表明,适量β-SiC晶须的加入可以有效提高固化树脂的拉伸模量和弯曲模量,并降低断裂伸长率;使用β-SiC晶须改性的树脂体系仍可保持较高的抗冲击性能和断裂韧性;固化树脂的最大分解速率对应的温度随着SiC晶须含量的增加而升高,最大分解速率随着SiC晶须含量的增加而减小,加入β-SiC晶须体系的玻璃化转变温度最大可以达到308℃,体系的耐热性能得到提高。

Abstract: In this paper, submicron β-SiC whisker was first treated with a silane coupling agent (KH550) and then introduced into a ternary-bismaleimide system (BDM/ BPA-BMI /DABPA). The tensile and bend moduli of the cured resin were improved effectively and the elongation at break was reduced because of the presence of β-SiC whisker.The impact and fracture toughness of the resin was not changed.With increasing of β-SiC whisker content,the temperature of maximum degration rate of the cured resin increased and the maximum degradation rate decreased.The introduction of β-SiC whisker increased the glass transition temperature (Tg) of cured resin and the maximum Tg value reached 308℃. The thermal stability and heat resistance of the cured resin were improved.

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