中国塑料 ›› 2016, Vol. 30 ›› Issue (12): 35-40 .DOI: 10.19491/j.issn.1001-9278.2016.12.007

• 材料与性能 • 上一篇    下一篇

乙烯-乙酸乙烯酯共聚物增韧改性聚甲醛的研究

沈晓洁,邱桂学   

  1. 青岛科技大学高分子科学与工程学院橡塑重点实验室
  • 收稿日期:2016-09-12 修回日期:2016-10-04 出版日期:2016-12-26 发布日期:2016-12-26

Study on Ethylene-vinyl Acetate Copolymer Toughed Polyacetal

  • Received:2016-09-12 Revised:2016-10-04 Online:2016-12-26 Published:2016-12-26

摘要: 通过熔融共混的方法制备了聚甲醛(POM)/乙烯-乙酸乙烯酯(EVA)共混物,并对共混物的力学性能、结晶性能以及形貌进行了研究。结果表明,纯POM的缺口冲击强度只有7.6 kJ/m2,加入EVA橡胶后,共混物的缺口冲击强度得到了明显提高,但随着橡胶用量的增加,材料的弯曲模量与拉伸强度不断下降;EVA 的存在影响着POM的结晶性能,使结晶度下降;POM与EVA的两相界面比较清晰,表明两者的相容性不好,但合适的分散相粒径分布有利于EVA增韧POM。

关键词: 聚甲醛, 乙烯-醋酸乙烯酯, 增韧, 力学性能, 结晶性能, 形貌

Abstract: Polyacetal (POM)/ethylene-vinyl acetate copolymer(EVA)compounds were melt blended by a twinscrew extruder. Mechanical properties, crystallinity and morphologies of the compounds were investigated. The results indicated that notched impact strength of the compounds was improved effectively with addition of EVA and increased with the EVA content, but their flexural modulus and tensile strength decreased gradually. The presence of EVA influenced the crystallization behavior of POM and resulted in a decrease in crystallinity of POM. Transmission electron microscopic observation revealed a clear interface between the two phases, indicating poor compatibility between the two polymers. However, a wide particle-size distribution was observed for the dispersed phase, which may favor the toughening of POM.

Key words: polyacetal, ethylene-vinyl acetate copolymer, toughening, mechanical property, crystallinity, morphology