China Plastics ›› 2014, Vol. 28 ›› Issue (05): 37-41 .DOI: 10.19491/j.issn.1001-9278.2014.05.007

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Effect of Fe2O3-coated Mica on Non-isothermal Crystallization Kinetics of PET

  

  • Received:2013-12-11 Revised:2014-02-24 Online:2014-05-26 Published:2014-05-26

Abstract: The non-isothermal crystallization behavior of poly(ethylene terephthalate)was investigated by differential scanning calorimetry (DSC), using Fe2O3-coated mica was used as a nucleating agent. Jeziorny and Mo methods were used to analyze the non-isothermal crystallization process of neat PET and composite of PET/Fe2O3-coated mica, and the activation energies of the systems were calculated by Flynn-Wall-Ozawa method. The results showed that the Fe2O3-coated mica acted as an efficient nucleating agent, and the crystallization rate of PET was obviously increased. Mo method appropriately described the non-isothermal crystallization of PET and the PET/ Fe2O3-coated mica composite. The incorporation of Fe2O3-coated mica particle did not obviously change the nucleation and crystal growth mechanism of PET,and simply decreased the crystallization activation energy of PET.

Key words: poly(ethylene terephthalate), iron oxide coated mica, non-isothermal crystallization kinetics, activation energy