China Plastics ›› 2008, Vol. 22 ›› Issue (07): 21-26 .DOI: 10.19491/j.issn.1001-9278.2008.07.004

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Compatibilization Effect of PP-g-(MAH/VAc) on Polypropylene/Polyamide 6 Blends

QIU Dun-rui,SUN Yu-feng,LI Shu-run,YANG Wan-tai   

  1. College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029,China
  • Received:2008-04-11 Revised:1900-01-01 Online:2008-07-26 Published:2008-07-26

Abstract: Scanning electron microscopy(SEM),differential scanning calorimctry (DSC) and mcchanical performance testing were used to investigate the compatibilization of polypropylene(PP)Polyamidc6(PA6)blends containing various polypropylene grafted malcic anhydride and vinyl acetate(PP-g-
MAH/VAc.SEM images indicated that the domains of PA6 dispersed in the PP/PA6/PP-g-(MAH/VAc) blends were significantly reduced to less than 5 μm.As 8%PP-g-MAH/VAc graft polymer with5.3%malcic anhydride-co-vinyl acetate was added as a compatibilizer in the blend of PP(80%)and Pn6 (20%),its elongation at break, tensile strength,and notched impact strength reached 558%,60.88 MPa, and to 5.28 kJ /㎡,respectively. The improved compatibility in PP/PA6/PP-g-(MAH/VAc) blends was attributed to the formation of PP/PA6 copolymer by chemical reactions between anhy-
dridc of MAH in PP-g-(MAH/VAc) and terminal amino groups of PA6 during the melt mixing, as confirmed by FTIR results.

Key words: polypropylene, polyamide 6, graft copolymer, compatibilization