中国塑料 ›› 2008, Vol. 22 ›› Issue (1): 1-6 .DOI: 10.19491/j.issn.1001-9278.2008.01.001

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国产高抗冲、透明丁苯树脂的性能、加工工艺及应用和发展前景

陈英林,刘青   

  1. 广东众和化塑有限公司,广东茂名525021
  • 收稿日期:2007-09-23 修回日期:1900-01-01 出版日期:2008-01-26 发布日期:2008-01-26

Properties,Processing,Application and Development Prospect of Domestic Transparent and Impact Butadiene-Styrene Resin

CHEN Ying-lin,LIU Qing   

  1. Guangdong Sunion Chemical&Plastics Co.Ltd.,Maoming 525021,China
  • Received:2007-09-23 Revised:1900-01-01 Online:2008-01-26 Published:2008-01-26
  • Contact: CHEN Ying-lin

摘要: 详细介绍了国内首套万吨级丁苯透明抗冲树脂装置所生产产品的力学性能、热性能和光学性能。丁苯树脂含有顺、反一1,4一丁二烯、1,2一丁二烯结钩、苯乙烯嵌段和无规嵌段等结钩,相对分子质量约1.1X10^5,呈单峰、双峰、二峰或五峰分布,可用来改善通用聚苯乙烯的脆性,同时还保持了透明性。该产品可广泛应用于日常用品和医用品等领域,可在传统的加工设备上进行注射成型、挤出成型、中空吹塑和热成型等加工,产品汗发和应用方向是高功能化和令用化。

关键词: 丁苯树脂, 透明, 阴离子聚合物, 加工, 应用

Abstract: This paper introduces the mechanical,thermal and optic properties of a high-impact,transparent styrene-butadiene resin manufactured from the first domestic 10 000-ton facilities, which was compared with those of similar forci}n products. The molecules of the resin contains various segments, such as cis,trans一1,4-butadiene,1,2-butadiene,homo一polystyrene,and random copolymcrizcd blocks of styrene and butadiene. The molecular weight is about 110 000,which can be mono-modal,bi一modal,tri一modal or pent-modal distributed.Both ductile and transparent characters arc achieved. This resin can be processed via traditional injection molding,extrusion,blow molding and thermoforming techniques for products in daily foods and medical areas.

Key words: butadiene-styrene resin, transparency, anionic polymer, processing, application