中国塑料

中国塑料 ›› 2008, Vol. 22 ›› Issue (05): 71-73 .DOI: 10.19491/j.issn.1001-9278.2008.05.015

• 助剂 • 上一篇    下一篇

甘油锌用作PVC热稳定剂的研究

申雄军，周忠诚，舒万良   

  1. 1.长沙理工大学化学与环境工程学院，湖南长沙410076; 2.中南大学化学化工学院，湖南长沙410083
  • 收稿日期:2007-12-05 修回日期:1900-01-01 出版日期:2008-05-25 发布日期:2008-05-25

Study of Glyzinc as Thermal Stabilizer for PVC

SHEN Xiong-jun，ZHOU Zhong-cheng，SHU Wang-Gen   

  1. college of Chemical and Environmental Engineering, Changsha University of Science and Technology,Changsha 410076，China; 2. College of Chemistry and Chemical Engineering,Central South University, Changsha 410083，China
  • Received:2007-12-05 Revised:1900-01-01 Online:2008-05-25 Published:2008-05-25
  • Contact: SHEN Xiong-jun

摘要： 运用刚果红试纸法、热烘箱老化实验法和流变仪试验，以硬脂酸锌作对比，对甘油锌配合物(简称甘油锌)用作聚氯乙烯(PVC)热稳定剂的热稳定作用进行了研究，并对甘油锌的复配进行了研究;还研究了稳定剂对PVC耐候性的影响。结果表明，甘油锌与硬脂酸钙在质量比为1.0/1.5时具有较好的协同作用，甘油锌/硬脂酸钙与环氧大豆油和业磷酸三苯酯质量比为1.0/1.5/0.2/0.2时有较好的协同效应;所研究的甘油锌/硬脂酸钙复合热稳定剂对PVC具有较好的热稳定作用,PVC与复合热稳定剂质量比为100.0/2.9时，PVC的刚果红试验热稳定时间达25min、热烘老化试验热稳定时间达130min.另外，研究发现环氧大豆油和亚磷酸二苯酯对硬脂酸锌/硬脂酸钙复合热稳定剂也有较好的协同效应。

关键词: 甘油锌, 聚氯乙烯, 热稳定作用, 协同效应

Abstract: Comparing with zinc stcarate, the thermal and weather stabilization effect of glyzinc compound (glyzinc for short) for PVC was investigated by Gongo red，heating aging, and rhcometer experimenu. The synergistic effect of glyzinc compounding with epoxy soybean oil and triphenyl phosphitc was investigated. When the weight ratio of glyzinc compounding, calcium stcarate, epoxy soybean oil，and triphcnyl phosphitc was 1.0 /1.5 /0.2 /0.2，and the loading of the compound stabilitizcr in PVC was 2. 9 phr, excellent thermal stabilization was obtained.In addition, the synergistic effect among zinc stcarate, calcium stcarate, epoxy soybean oil，triphcnyl phosphitc was also observed.

Key words: glyzinc, poly(vinyl chloride), thermal stability, synergistic effect

京公网安备11010802034965号　 京ICP备13020181号-2
《中国塑料》编辑部 ©2008-2023 版权所有
地址:北京市海淀区阜成路11号　邮编：100048
编辑部：010-68985541　联系信箱：cp@plaschina.com.cn
广告部/发行部：010-68985253　本系统由北京玛格泰克科技发展有限公司设计开发