中国塑料 ›› 2009, Vol. 23 ›› Issue (04): 32-35 .DOI: 10.19491/j.issn.1001-9278.2009.04.008

• 材料与性能 • 上一篇    下一篇

SEBS-g-MA对PS/PA6共混物的相形态和动态流变行为的影响研究

张德强 唐斌 丁雪佳 吴恒澜 李洪波 薛海蛟   

  1. 北京化工大学材料科学与工程学院 北京化工大学 北京化工大学
  • 收稿日期:2008-12-11 修回日期:1900-01-01 出版日期:2009-04-26 发布日期:2009-04-26

Morphologies and dynamic rheological behavbior of Polystyrene/Polyamide 6 blend and their blends compatibilized with styrene-ethylene/butylene-styrene elastomer grafted with maleic anhydride

DING xuejia deqiang zhang bin tang hongbo li haijiao xue   

  • Received:2008-12-11 Revised:1900-01-01 Online:2009-04-26 Published:2009-04-26
  • Contact: DING xuejia

摘要: 采用马来酸酐接枝氢化苯乙烯-丁二烯嵌段共聚物(SEBS-g-MA)改性聚苯乙烯(PS)/尼龙6(PA6)共混物。SEM观察共混物相态发现,随着SEBS-g-MA加入量的增加,PS/PA6双连续相结构并未改变,而PS和PA6的相畴尺寸逐渐变小,加入量超过10%以后,相畴尺寸出现变大的趋势。动态流变测试表明,PS/PA6共混物熔体的复数粘度、储能模量及损耗模量均随SEBS-g-MA的加入而增加,即SEBS-g-MA同时提高了体系的粘性和弹性,但是体系的粘弹比却出现下降,且随加入量的增多,作用程度更为显著。

关键词: 聚苯乙烯, 尼龙6, 马来酸酐接枝氢化苯乙烯-丁二烯嵌段共聚物, 双连续, 动态流变

Abstract: The blends of Polystyrene/Polyamide6 compatibilized by styrene-ethylene/butylene-styrene elastomer grafted with maleic anhydride were prepared by melt blending. The phase morphologies were investigated using scanning electron microscope (SEM). As the content of SEBS-g-MA increased, although the phase morphology of co-continuous PS/PA6 didn’t change, the phase size became smaller. However, when the content of SEBS-g-MA exceeded 10%, the phase size tended to larger. The reasearch on dynamic rheology found that the complex viscosity (η*), storage modulus and loss modulus became higher because of the addtion of SEBS-g-MA. That is, incorporation of SEBS-g-MA improved the viscosity and elasticity. It also indicated that the more the addtion amount of SEBS-g-MA, the smaller viscosity-elasticity rate. Keywords: Polystyrene;Polyamide6;styrene-ethylene/butylene-styrene elastomer grafted with maleic anhydride; co-continuous; dynamic rheology

Key words: Polystyrene, Polyamide6, styrene-ethylene/butylene-styrene elastomer grafted with maleic anhydride, co-continuous, dynamic rheology

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