中国塑料 ›› 2011, Vol. 25 ›› Issue (05): 55-59 .DOI: 10.19491/j.issn.1001-9278.2011.05.012

• 材料与性能 • 上一篇    下一篇

ABS树脂湿法挤出工艺及产品力学性能的研究

牛秋生 刘振国 徐刚 张会轩 杨海东   

  1. 1长春工业大学化工学院2中国科学院长春应用化学研究所
  • 收稿日期:2010-11-15 修回日期:2011-03-22 出版日期:2011-05-26 发布日期:2011-05-26

Study on Wet Extrusion Process and Mechanical Property of ABS Resin

  

  • Received:2010-11-15 Revised:2011-03-22 Online:2011-05-26 Published:2011-05-26

摘要: 采用湿法挤出工艺,即将乳液聚合合成的经凝聚和过滤的丙烯腈-丁二烯-苯乙烯(ABS)湿粉料与苯乙烯-丙烯腈共聚物(SAN)树脂以一定的比例投入湿法挤出机内挤出造粒,直接获得了ABS树脂。考察了ABS粉料含水量、ABS树脂中橡胶含量、抗氧剂含量、挤出机温度及螺杆转速等因素对ABS树脂力学性能的影响。结果表明,挤出温度过高明显引起物料降解,ABS树脂的冲击强度减小,拉伸强度降低;ABS粉料含水量对ABS树脂的性能没有明显影响;透射电子显微镜分析表明,橡胶粒子在SAN基体中分散均匀;湿法挤出的最佳工艺参数为,挤出温度:180 ℃,螺杆转速:200 r/min,抗氧剂含量:0.154 %(质量分数,下同)。

关键词: 丙烯腈-丁二烯-苯乙烯树脂, 湿法挤出, 工艺, 力学性能

Abstract: In this paper, wet extrusion process was used to prepare ABS resin. Firstly, ABS graft copolymer wet powder was synthesized by emulsion polymerization, and then filtering, dewatering. Secondly, the ABS graft copolymer wet powder was blended with SAN resin and then extruded in wet extruder, getting the ABS resin. The effects of moisture, rubber content, antioxidant content, and extrusion temperature and screw rotating speed on mechanical properties of ABS resin were studied. It was found that a too high extrusion temperature caused the degradation of the resin, the impact and tensile strengths decreased with increasing extrusion temperature. The moisture content had little effect on the mechanical property of ABS resin. TEM showed that rubber particles dispersed in the SAN matrix uniformly. The optimum parameters in the processing were extrusion temperature 180 °C, screw rotating speed 200 r/min, and antioxidant content 0.154 wt %.

Key words: acrylonitrile-butadiene-styrene resin, wet extrusion, processing condition, mechanical property