中国塑料 ›› 2011, Vol. 25 ›› Issue (05): 65-69 .DOI: 10.19491/j.issn.1001-9278.2011.05.014

• 加工与应用 • 上一篇    下一篇

改性AC发泡剂对PVC木塑复合材料力学性能影响

白晓艳 王清文 隋淑娟   

  1. 内蒙古呼伦贝尔市呼伦贝尔学院生命科学与化学学院 东北林业大学
  • 收稿日期:2010-09-28 修回日期:2011-02-06 出版日期:2011-05-26 发布日期:2011-05-26

Effect of Modified AC Foaming Agent

  

  • Received:2010-09-28 Revised:2011-02-06 Online:2011-05-26 Published:2011-05-26

摘要: 采用动态热流式差示扫描量热仪对自制改性偶氮二甲酰胺(AC)发泡剂进行了分析,并研究了其用量对聚氯乙烯(PVC)木塑复合材料力学性能的影响。结果表明,该改性AC发泡剂的分解温度在165~187 ℃,与传统AC发泡剂相比分解温度降低约40 ℃,且峰值放热量降低了39.5 %;改性AC发泡剂的平均发气量为189 mL/mg;扫描电子显微镜分析表明,使用1.2份改性AC发泡剂时获得的PVC木塑复合材料的泡孔致密均匀,明显优于使用未改性AC发泡剂的情况;与未发泡的材料相比,使用1.2份改性AC发泡剂时, PVC木塑复合材料的冲击强度提高了34.6 %,表观密度降低了22.5 %。

关键词: 力学性能, 聚氯乙烯, 偶氮二甲酰胺, 木塑复合材料, 发泡剂, 改性

Abstract: Performance of homemade modified azodicarbonamide(AC) foaming agent in PVC/wood composites was studied using differential scanning calorimeter. It was shown that the decomposition temperature of modified AC foaming agent was in the range from 165 ℃ to 187 ℃. Compared with the traditional AC foaming agent, the decomposition temperature was reduced by 40 ℃ and peak exothermic was also reduced about 39.5 %. The average gas evolution of modified AC was 189 mL/mg .When 1.2 phr modified AC foaming agent was used, fine and uniform pores were obtained, which was witnessed by scanning electron microscope (SEM) micrographs. Compared with un-foamed PVC/wood composites, the impact strength of foamed composites increased by 34.6 % and apparent density decreased by 22.5 %

Key words: mechanical properties, poly(vinyl chloride), azodicarbonamide, wood-plastic composite, foaming agent, modification