中国塑料 ›› 2011, Vol. 25 ›› Issue (09): 75-78 .DOI: 10.19491/j.issn.1001-9278.2011.09.016

• 加工与应用 • 上一篇    下一篇

PE-HD在应力场中的双向自增强研究

袁毅 徐绍虎 崔爽 申开智   

  1. 重庆工商大学机械工程学院 四川大学高分子学院
  • 收稿日期:2011-06-13 修回日期:1900-01-01 出版日期:2011-09-26 发布日期:2011-09-26

Study on Two-dimensional Self-reinforcement of PE-HD in Two-dimensional Compound Stress Field

Yi YUAN Shaohu XU Shuang CUI Kaizhi SHEN   

  • Received:2011-06-13 Revised:1900-01-01 Online:2011-09-26 Published:2011-09-26
  • Contact: Kaizhi SHEN

摘要: 利用自制的剪切拉伸双向复合应力场挤管装置生产出了双向自增强的高密度聚乙烯(PE-HD)管材,研究分析了该双向应力场对PE-HD管材的拉伸强度、微观分子取向和结晶度的影响。结果表明,剪切拉伸双向复合应力场能实现管材轴周向性能的双向自增强,提高管材分子的取向度和结晶度。其轴向拉伸强度最高增强到25.82 MPa,提高了14.8 %;周向拉伸强度最高增强到24.52 MPa,提高了13 %;管材分子由明显的球晶结构转变为高度取向的串晶结构;结晶度达到71.95 %。

关键词: 高密度聚乙烯, 剪切拉伸双向复合应力场, 双向自增强, 取向, 结晶

Abstract: Through a shearing-drawing two-dimensional stress field applied in a pipe-extrusion die developed by this group, two-dimensional self-reinforcement high density polyethylene (PE-HD) pipe was prepared. The tensile strength, molecule orientation and crystallinity of the pipe were studied. It showed that the two-dimensional stress field improved the molecule orientation and crystallinity, the circular and axial tensile strengths of the pipe were improved simultenously. The best circular and axial tensile strength were 24.52 MPa and 25.82 MPa, increased by 13 % and 14.8%, respectively, based on regular pipe. The crystallinity was increased to 71.95 % and the improvement was 8.2 %. A shish kebab structure was observed.

Key words: high density polyethylene, shearing-drawing two-dimensional compound stress field, two-dimensional self-reinforcement, orientation, crystallinity