中国塑料 ›› 2011, Vol. 25 ›› Issue (12): 86-89 .DOI: 10.19491/j.issn.1001-9278.2011.12.023

• 塑料与环境 • 上一篇    下一篇

粉煤灰提取Al2O3及其改性聚丙烯的研究

董金虎   

  1. 陕西理工学院
  • 收稿日期:2011-08-04 修回日期:1900-01-01 出版日期:2011-12-26 发布日期:2011-12-26

Research on Al2O3 Component Extracted from Fly Ash and Modify PP

DONG Jinhu   

  • Received:2011-08-04 Revised:1900-01-01 Online:2011-12-26 Published:2011-12-26
  • Contact: DONG Jinhu

摘要: 采用碱焙烧法从粉煤灰中提取Al2O3,将提取的Al2O3用于聚丙烯(PP)改性研究,并以市售Al2O3改性的PP为参考,考察了Al2O3对PP力学性能、微观形态的影响。结果表明,提取的Al2O3改性PP的拉伸性能和冲击性能与市售Al2O3相当;当Al2O3含量增加到2 %时,PP的拉伸断面均由平整结构变为轻微的层状结构,此时拉伸和冲击性能达到最佳,拉伸强度提高约6 %、伸长率提高约23 %、冲击强度提高约14 %;当Al2O3含量继续增加到5 %时,层状结构更为明显,改性PP的冲击强度急剧下降。

关键词: 粉煤灰, 三氧化二铝, 聚丙烯, 改性

Abstract: Al2O3 was extracted from fly ash via high-temperature alkali calcinations. The properties of PP containing such extracted Al2O3 were compared with commercial PP/Al2O3 resins. It showed that, the tensile and impact properties of PP/extracted Al2O3 were similar to commercial resins. When the content of the extracted Al2O3 increased to 2 %, the microstructure of PP matrix change from smooth structure to slight lamellar structure, and the tensile strength, elongation at break, and impact strength increased by 6 %, 23 %, and 14 %, respectively, based on neat PP. However, when the content of extracted Al2O3 increased to 5%, the impact strength of PP decreased dramatically.

Key words: Fly ash, aluminum oxide, polypropylene, modification