中国塑料 ›› 2015, Vol. 29 ›› Issue (10): 83-87 .DOI: 10.19491/j.issn.1001-9278.2015.10.016

• 助剂 • 上一篇    下一篇

含异氰酸基表面改性剂制备及其在PVC/木粉材料中的应用

仇卓威1,倪忠斌1,陈明清2,刘士荣1   

  1. 1. 江南大学化学与材料工程学院2. 江南大学
  • 收稿日期:2015-05-13 修回日期:2015-07-03 出版日期:2015-10-26 发布日期:2015-10-26

Synthesis of a Surface Modifier Containing Isocyanate on Poly(vinyl chloride)/Wood Powder Composites

  • Received:2015-05-13 Revised:2015-07-03 Online:2015-10-26 Published:2015-10-26

摘要: 以异氰酸酯与脂肪醇为原料,制备了含异氰酸基表面改性剂,并研究了该改性剂对聚氯乙烯(PVC)/木粉复合材料力学性能及加工性能的影响。结果表明,通过3 %表面改性剂改性以后的木粉,其表面接触角能够达到146.0 °;相对于由未改性木粉制备的PVC/木粉复合材料,由改性木粉制备的PVC/木粉复合材料,拉伸强度提高了32.6 %,断裂伸长率提高了42.1 %;PVC/改性木粉复合材料的塑化时间从57.5 s缩短至46.7 s,平衡扭矩从24.7 N·m减小到18.2 N·m,塑化温度从147.3 ℃降低到了140.4 ℃;随着碳链的增长,改性剂的改性效果也随之优化。

关键词: 表面改性剂, 异氰酸酯, 聚氯乙烯, 木粉

Abstract: In this study, a kind of surface modifiers was synthesized from isocyanate and aliphatic alcohol and was used in poly(vinyl chloride) based woodplastic composites(WPC). After treated with 3 % surface modifier, the surface water contact angle of wood flour increased to 146.0°, and the tensile strength of WPC increased by almost 32.6 % and the elongation at break increased by more than 42.1 %. The plasticizing time of WPC decreased from 57.5 s to 46.7 s, the equilibrium torque decreased from 24.7 to 18.2 N·m, and the plasticizing temperature decreased from 147.3 to 140.4 ℃. In addition, the longer the carbon chain length of aliphatic alcohol, the better the surface modification effect of the surface modifier.

Key words: surface modifier, isocyanate, poly (vinyl chloride), wood flour