中国塑料 ›› 2016, Vol. 30 ›› Issue (02): 11-19 .DOI: 10.19491/j.issn.1001-9278.2016.02.003

• 综述 • 上一篇    下一篇

自组装功能高分子材料表面的相互作用

张敏1,许小玲1,宋吉青2,何文清2   

  1. 1. 陕西科技大学2. 中国农业科学院农业环境与可持续发展研究所
  • 收稿日期:2015-09-14 修回日期:2016-01-11 出版日期:2016-02-26 发布日期:2016-02-26

Surface Interaction of Selfassembly Functional Polymeric Materials

  • Received:2015-09-14 Revised:2016-01-11 Online:2016-02-26 Published:2016-02-26

摘要: 分析了氢键作用、范德华能、静电作用能、交换排斥能等高分子材料表面的相互作用及其影响因素,综述了自组装纳米材料、自组装嵌段共聚物和自组装生物大分子材料等功能高分子材料表面的相互作用,讨论了表面的相互作用类型和强弱对其自组装机理、结构、性能的影响,展望了新型功能高分子材料的开发和发展方向。

关键词: 自组装, 相互作用, 纳米材料, 嵌段共聚物, 生物大分子

Abstract: The surface interaction of polymers and its influencing factors such as hydrogenbond interaction,van der Waals energy, electrostatic interaction, and dipoledipole force were analysed. The surface interaction of functional materials such as selfassembly nanomaterials, selfassembly block copolymers and selfassembly biological macromoleculars was introduced. In addition, the effects of selfassembly mechanism, the structure and performance were analyzed according to interaction types and interface strength. Furthermore, the development, application prospect and potential values of new functional polymeric materials were presented.

Key words: self-assembly, interaction, nano materials, block copolymers, biological macromolecules