中国塑料 ›› 2016, Vol. 30 ›› Issue (03): 88-93 .DOI: 10.19491/j.issn.1001-9278.2016.03.016

• 助剂 • 上一篇    下一篇

增容剂DT对PLA/PBAT共混物性能的影响

甄智勇1,张陆祥2,裘煜2,裘陆军2,戴文利3   

  1. 1. 湘潭大学化学学院高分子材料研究所2. 浙江天禾生态科技有限公司3. 湘潭大学化学学院
  • 收稿日期:2015-11-13 修回日期:2015-12-20 出版日期:2016-03-26 发布日期:2016-03-26

Effect of Compatibilizer DT on Properties of PLA/PBAT Blends

  • Received:2015-11-13 Revised:2015-12-20 Online:2016-03-26 Published:2016-03-26

摘要: 以不饱和酯类化合物(DT)为增容剂,通过双螺杆挤出机反应性挤出制备聚乳酸(PLA)/聚己二酸对苯二甲酸丁二酯(PBAT)共混物。采用扫描电子显微镜、旋转流变仪、偏光显微镜、差示扫描量热仪、热重分析仪和万能试验机讨论DT对共混物相容性、结晶性能、热失重以及力学性能的影响。结果表明,适量的DT增加了两相之间界面黏结,有效改善了PLA和PBAT之间相容性;当DT添加量为0.3 %(质量分数,下同)时,断裂伸长率增加了46.3 %,冲击强度显著增加,冲击试样未完全断裂。

关键词: 聚乳酸, 聚己二酸对苯二甲酸丁二酯, 增容剂, 结晶, 韧性

Abstract: An unsaturated ester compound(DT) was added to poly(lactic acid) (PLA)/poly(butylene adipatecoterephthalate) (PBAT) blends as a compatibilizer through a twin screw extruder. The influence of DT on the compatibility, crystallization behavior, thermogravimetric and mechanical properties were investigated by scanning election microscope, rotational rheometer, polarized optical microscope, differential scanning calorimetry, thermal gravimetric, and mechanical property tests. It was found that interface adhesion was increased with moderate DT and contributed to a preferable compatibility between PLA and PBAT. Elongation at break increased by 46.3 % while adding 0.3 wt% DT, and the same amount of DT gave rise to the excess of impact strength measuring range.

Key words: poly(lactic acid), poly(butylene adipate-co-terephthalate), compatibilizer, crystallization, toughness