中国塑料 ›› 2017, Vol. 31 ›› Issue (1): 13-19 .DOI: 10.19491/j.issn.1001-9278.2017.01.003

• 材料与性能 • 上一篇    下一篇

有机硅氧烷对乘用车专用阻尼材料的性能影响

肖艳丽1,刘福2,王国芝1,周琴琴2,汪晓东1   

  1. 1. 北京化工大学2. 马鞍山联洪合成材料有限公司
  • 收稿日期:2016-09-07 修回日期:2016-10-24 出版日期:2017-01-26 发布日期:2017-01-26

Effects of Organosilicon on Microstructure and Properties of Waterborne Damping Materials for Vehicles

  • Received:2016-09-07 Revised:2016-10-24 Online:2017-01-26 Published:2017-01-26
  • Contact: Xiao-Dong WANG

摘要: 将乙烯基有机硅氧烷、苯乙烯、丙烯酸丁酯及甲基丙烯酸等单体共聚,制备了不同配比的丙烯酸酯共聚乳液,并在乳液中加入无机填料,在多种助剂配合下制备出了性能优良的复合阻尼材料。采用傅里叶红外光谱仪和动态力学分析仪研究了共聚乳液中有机硅氧烷组分对乳胶膜的结构、阻尼性能和复合材料的损耗因子的影响,通过扫描电子显微镜对比研究了经有机硅氧烷改性前后的乳胶粒的变化以及改性前后丙烯酸酯乳液与填料的界面相容性,并研究了有机硅氧烷对阻尼材料的力学性能的影响。结果表明,当共聚乳液组成中含有一定量的有机硅氧烷进行改性后,乳胶膜的阻尼性能、丙烯酸酯乳液与填料的相容性以及阻尼材料的力学性能均得到明显的改善。

关键词: 有机硅氧烷, 阻尼材料, 丙烯酸酯乳液, 相容性, 力学性能

Abstract: The acrylate copolymer latexes containing different contents of organosilicon were synthesized by emulsion polymerization and then characterized by Fouriertransform infrared spectroscopy. Their morphologies and dynamic mechanical properties were investigated by scanning electron microscopy (SEM) and dynamic mechanical analysis (DMA), respectively. A series of waterborne damping materials for vehicles were prepared by compounding the resulting copolymer latexes with inorganic fillers. SEM observation demonstrated that the incorporation of organosilicon could improve the compatibility between the copolymer latexes and inorganic fillers and thus resulted in a better interfacial combination between them. DMA investigation showed that the damping properties of the damping materials were enhanced significantly. Moreover, the mechanical properties of the damping materials also presented a remarkable improvement due to the addition of organosilicon.

Key words: organosilicon, damping material, acrylate copolymer latexes, compatibility, mechanical property