复合聚全氟乙丙烯材料的介电及高频击穿性能研究

doi:10.19491/j.issn.1001-9278.2008.02.007

中国塑料 ›› 2008, Vol. 22 ›› Issue (02): 33-36 .DOI: 10.19491/j.issn.1001-9278.2008.02.007

复合聚全氟乙丙烯材料的介电及高频击穿性能研究

胡巧青，范晓东，朱光明，颜红侠

西北工业大学理学院应用化学系，陕西西安710072

收稿日期:2007-09-22 修回日期:1900-01-01 出版日期:2008-02-26 发布日期:2008-02-26

Study on Dielectric Properties and Nigh-frequency Breakdown Performance of FEP Composites

HU Qiao-qing，FAN Xiao-dong，ZHU Guang-ming，YAN Hong-xia

Department of Applied Chemistry, College of Science, Northwestern Polytechnical University, Xi an 710072 , China

Received:2007-09-22 Revised:1900-01-01 Online:2008-02-26 Published:2008-02-26
Contact: HU Qiao-qing

摘要/Abstract

摘要： 在聚全氟乙丙烯(FEP)中添加TiO2和Al2O3，通过热压成型的方法制备了FEP/Ti02复合材料和FEP/Al2O3复合材料，研究了氧化物添加量对复合材料介电常数、介电损耗和高频击穿性能的影响。结果表明，随氧化物含量的增加，复合材料的介电常数和介电损耗均增加;在同一添加量下，Ti02对复合体系的介电性能影响较大。FEP/Ti02复合材料的高频击穿性能随Ti02含量的增加而下降，在Ti02含量为4.0%(质量分数，下同)时，复合材料的损伤阂值已降为FEP材料损伤阂值的48.9%。而FEP/Al2O3姚复合材料的高频击穿性能随}z钱含量的增加而升高，当从姚含量为1.2%时，复合材料的损伤阂值已增大到FEP材料损伤阂值的2倍，达到313J/m2.

关键词: 聚全氟乙丙烯, 二氧化钦, 三氧化二铝, 介电性能, 高频击穿性能

Abstract: Composites of perfluorinated ethylene-propylene copolymer (FEP) with Ti02 and Al2O3 were prepared via thermoforming. the effects of oxide content on dielectric constant, dielectric loss, and high-frequency breakdown performance of the composites were studied. the dielectric constant and loss of FEP composites increased with increasing oxide content, with the influence of Ti02 being more obvious. Ti02 possessed a negative effect on the high-frequency breakdown performance. At 4. 0 wt，the damage threshold of FEP/Ti02 composite was only 48. 9%that of neat FEP. In contrast, the high-frequency breakdown performance increased with increasing Al2O3 content. When the content of Al2O3 was 1 .2 wt，the damage threshold of FEP/Al2O3 composite reached 313 J/m2，that was twice that of neat FEP.

Key words: fluorinated ethylene propylene, titanium dioxide, aluminum oxide, dielectric performance, high-frequency breakdown performance

胡巧青, 范晓东, 朱光明, 颜红侠. 复合聚全氟乙丙烯材料的介电及高频击穿性能研究[J]. 中国塑料, 2008, 22(02): 33-36 .

HU Qiao-qing, FAN Xiao-dong, ZHU Guang-ming, YAN Hong-xia. Study on Dielectric Properties and Nigh-frequency Breakdown Performance of FEP Composites [J]. China Plastics, 2008, 22(02): 33-36 .

[1]	姚军龙, 王新瑞, 胡立, 江学良, 游峰, 周敏. 酒石酸改性BT增强PP复合材料导热与介电性能[J]. 中国塑料, 2021, 35(4): 30-34.
[2]	罗轩昂, 刘述梅, 赵建青. 低介电损耗环氧树脂复合材料的研究进展[J]. 中国塑料, 2021, 35(3): 130-138.
[3]	杨富凯, 张玉迪, 邓玉媛, 徐新宇. 聚酰亚胺泡沫材料的性能研究概述[J]. 中国塑料, 2020, 34(11): 94-101.
[4]	张营堂, 童婷, 马飞, 袁新强, 包维维, 郝晓丽, 刘立柱. 聚偏氟乙烯的宽频介电谱特征研究[J]. 中国塑料, 2015, 29(08): 48-53 .
[5]	沈剑辉, 林海波, 向艳慧, 刘富, 薛立新. 纳米CaCO₃对FEP非等温结晶动力学的影响[J]. 中国塑料, 2015, 29(03): 38-44 .
[6]	李婷婷颜红侠王倩倩冯书耀. 氰酸酯/聚苯醚/超支化聚硅氧烷接枝纳米SiO₂复合材料的性能[J]. 中国塑料, 2014, 28(01): 22-27 .
[7]	陶国良, 张天奇, 马文中, 夏艳萍, 纪波印. PVDF/ TiO₂复合膜的性能及研究[J]. 中国塑料, 2013, 27(08): 56-60.
[8]	梅文杰, 熊玉竹, 刘振宇, . TiO₂在PP抗老化中的机理及研究进展[J]. 中国塑料, 2013, 27(01): 17-21.
[9]	董金虎. 粉煤灰提取Al₂O₃及其改性聚丙烯的研究[J]. 中国塑料, 2011, 25(12): 86-89 .
[10]	钟亮杨艳娟. 聚合物熔体的介电性能研究[J]. 中国塑料, 2009, 23(09): 40-43 .

复合聚全氟乙丙烯材料的介电及高频击穿性能研究

Study on Dielectric Properties and Nigh-frequency Breakdown Performance of FEP Composites

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 10

编辑推荐

Metrics

本文评价