中国塑料 ›› 2008, Vol. 22 ›› Issue (10): 13-19.DOI: 10.19491/j.issn.1001-9278.2008.10.003

• 综述 • 上一篇    下一篇

微-纳米无机粒子改性聚丙烯材料的最新进展

陈慧敏,陈德良,张 锐   

  1. 郑州大学材料科学与工程学院
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2008-10-25 发布日期:2008-10-25

Recent Development of Polypropylene Composites Modified with Micro-/Nano-Sized Inorganic Particles

CHEN Hui-min, CHEN De-liang, ZHANG Rui   

  1. School of Materials Science and Engineering, Zhengzhou University
  • Received:1900-01-01 Revised:1900-01-01 Online:2008-10-25 Published:2008-10-25
  • Contact: ZHANG Rui

摘要: 综述了近年来微-纳米无机刚性粒子填充改性聚丙烯(PP)材料的最新进展,介绍了微米级、纳米级和微-纳米组合无机刚性粒子的添加对PP复合材料性能的影响。无机刚性粒子越细,越有利于PP材料的增强增韧;无机刚性粒子的表面改性处理对复合材料的微观结构和性能有重要影响。微米无机刚性粒子可提高PP材料的抗冲击强度与刚性,但强度会有所降低;均匀分散的无机纳米粒子同时起到增强增韧的双重作用;具有粒径级的组合粒子的填充改性优于单一无机粒子。

关键词: 聚丙烯, 微-纳米无机刚性粒子, 增强, 增韧

Abstract: This paper reviews advances in the modification of PP-based composites with micro-/nano-sized inorganic rigid particles, with emphasis on reviewing the effects of micro-sized, nano-sized and micro-/nano-sized compounded inorganic particles on the mechanical and functional properties of the PP-based composites. A general conclusion is that the smaller the inorganic particles, the more favorable the composites are strengthened and toughened, and that the modification of the inorganic particles has a critical influence on the interfaces of the composites, which then affect the microstructures and properties remarkably. The addition of micro-sized inorganic particles can improve the impact property and rigidity of the PP-based composites, but usually reduces the strength properties; on the other hand, nano-sized inorganic particles have the ability to enhance the strength, toughness, and modulus of the PP-based composites. The properties of the PP composites filled with compounded fillers are better than those of the PP composites filled with single fillers.

Key words: polypropylene, micro-/nano-sized inorganic rigid particles, strengthening, toughening