›› 2023, Vol. 37 ›› Issue (3): 42-51.

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三维共价有机骨架膜合成、后修饰方法及CO2捕集的应用

蘧延庆,刘洋,查雨欣,谷桐,杜小雨,贾宏葛   

  1. 齐齐哈尔大学
  • 收稿日期:2022-11-03 修回日期:2022-12-28 出版日期:2023-03-26 发布日期:2023-03-26
  • 基金资助:
    青年创新人才项目

Synthesis and post?modification methods of three?dimensional covalent organic frameworks and their applications for CO2 capture

  • Received:2022-11-03 Revised:2022-12-28 Online:2023-03-26 Published:2023-03-26

摘要: 提出了基于环保理念的膜分离法对CO2气体进行捕集,其中共价有机骨架膜材料展现出其独特优势。目前,二维结构的有机骨架材料研究已经较为成熟。然而关于三维共价有机骨架材料(3D-COFs)的研究相对较少。综述了3D-COFs膜材料的合成方法和后修饰方法,同时讨论了3D-COFs膜材料在CO2捕集中的具体应用,并展望了3D-COFs膜材料未来的发展方向。

关键词: 三维共价有机骨架, 合成方法, 改性方法, 气体分离, 二氧化碳捕集

Abstract: A separation membrane based on the environmental protection concept was developed in this work. In this membrane, covalent organic framework (COF) membrane materials presented unique advantages. At present, the studies on the two-dimensional structure of COF materials are relatively mature; however, there are few studies on three-dimensional COF materials (3D-COFs). This paper introduced the synthetic and post-modification methods of 3D-COFs membrane materials and discussed the specific application of 3D-COFs membrane materials for CO2 capture. Finally, the future development direction of 3D-COFs membrane materials was prospected.

Key words: three-dimensional covalent organic frameworks, synthesis method, post-modification method, gas separation, carbon dioxide capture