›› 2023, Vol. 37 ›› Issue (4): 39-45.

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双组分聚氨酯嵌缝胶的制备与性能研究

吴文富1,王振军2,黄德辉1,李佳容2,边关2   

  1. 1. 广西南玉铁路有限公司
    2. 长安大学
  • 收稿日期:2023-01-06 修回日期:2023-01-31 出版日期:2023-04-26 发布日期:2023-04-26
  • 基金资助:
    陕西省重点研发计划项目;广西交通投资集团有限公司科研项目

Preparation and performance of two?component polyurethane sealant

  • Received:2023-01-06 Revised:2023-01-31 Online:2023-04-26 Published:2023-04-26

摘要: 为改善高速铁路嵌缝胶性能,以无机CaCO3为填料制备双组分聚氨酯(PU)嵌缝胶。采用扫描电子显微镜对不同CaCO3含量的PU嵌缝胶表面形貌进行观测,分析不同PU样品的力学性能、黏附性能变化规律,并评价其耐热性与耐水性。结果表明,掺入无机填料会降低PU嵌缝的表面平整度,增加其粗糙度;适量的CaCO3填料可提高PU嵌缝胶的拉伸强度、断裂伸长率以及模量,但过量的填料会降低其断裂伸长率;随着填料含量的提高,嵌缝胶的黏附性、耐水性以及耐热性亦显著提升;此外,综合PU嵌缝胶各项性能,推荐填料含量为30 %。研究成果为提高高速铁路PU嵌缝胶性能以及降低生产成本提供了一定参考。

关键词: 高速铁路, 聚氨酯嵌缝胶, 性能评价, 耐热性, 微观形貌

Abstract: Two-component polyurethane (PU) sealants with an inorganic CaCO3 filler were developed to improve the performance for use as a high-speed railway sealing sealant. The surface morphology of polyurethane sealants with different contents of the CaCO3 filler was observed using a scanning electron microscope. The mechanical and adhesion properties of the PU sealant samples were analyzed and their heat and water resistance were evaluated. The results indicated that the inorganic filler could reduce the surface flatness of the sealants but improved their roughness. The appropriate addition amount of the CaCO3 filler enhanced the tensile strength, elongation at break, and modulus of the sealants; however, the excessive amount of the filler reduced their elongation at break. With the addition of the filler, the adhesion, heat resistance, and water resistance of the sealants were all improved considerably. In addition, the addition amount of 30 wt% CaCO3 filler was recommended for the PU sealants to achieved optimal comprehensive performances. The findings in this study provide a reference for enhancing the cost-effectiveness and performance of PU-based high-speed railway sealing sealants.

Key words: high-speed railway, polyurethane sealant, performance evaluation, heat resistance, micro-morphology