›› 2023, Vol. 37 ›› Issue (7): 41-46.

• • 上一篇    下一篇

耐化学抗菌改性PC/TPU共混合金的制备及性能研究

邹永昆1,范温柔2,4,余彪3,郭森2,4,高天明2,4,何经纬5,刘芳5   

  1. 1. 广东美的厨卫电器制造有限公司
    2. 岭南师范学院化学化工学院
    3. 岭南师范学院
    4. 岭南师范学院化学化工学院
    5. 华南理工大学
  • 收稿日期:2023-02-06 修回日期:2023-04-06 出版日期:2023-07-26 发布日期:2023-07-26

Preparation and properties of chemica-resistant and antibacterial PC/TPU blends

  • Received:2023-02-06 Revised:2023-04-06 Online:2023-07-26 Published:2023-07-26

摘要: 以聚碳酸酯(PC)、热塑性聚氨酯弹性体(TPU)和抗菌剂为主要原料,利用熔融共混法制备了耐化学抗菌改性PC/TPU共混合金。系统地研究了TPU含量、硬度、类型和抗菌剂种类对材料性能的影响。结果表明,PC/TPU共混合金的加工流动性、缺口冲击强度及耐化学性能随TPU含量增大而提高。与聚醚型TPU相比,硬度更高的聚酯型TPU更有利于提高材料的缺口冲击韧性和化学稳定性。当加入0.6 %活性氧化锌时,PC/TPU共混合金对大肠杆菌和金黄色葡萄球菌的抗菌率大于99.9 %。

关键词: 聚碳酸酯, 热塑性聚氨酯弹性体, 耐化学, 抗菌, 缺口冲击强度

Abstract: The chemica-resistant and antibacterial polycarbonate (PC)/polyurethane elastomer (TPU) blends were prepared through melt blending using PC, TPU, and antibacterial agents as raw materials. The effects of the amount, hardness, type of TPU and type of antibacterial agent on the properties of the blends were systematically studied. The results indicated that the processing fluidity, notched impact strength and chemical resistance of the blends increased with an increase in the TPU content. Compared to the polyether?type TPU, the polyester?type TPU with a high hardness is more advantageous to improving the notched impact toughness and chemical stability of the blends. When 0.6 wt% active ZnO was added, the PC/TPU blends obtained an antibacterial rate of over 99.9 % against Escherichia coli and Staphylococcus aureus.

Key words: polycarbonate, thermoplastic polyurethane elastomer, chemical resistance, antibacterial, notched impact strength