中国塑料 ›› 2013, Vol. 27 ›› Issue (03): 96-99 .DOI: 10.19491/j.issn.1001-9278.2013.03.018

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膨胀石墨混杂填充聚丙烯复合材料导热性能研究

吴宏武 徐晓强 刘汉   

  1. 广东省广州市天河区华南理工大学聚合物新型成型装备国家工程研究中心;聚合物成型加工教育部重点实验室
  • 收稿日期:2012-11-14 修回日期:2012-12-24 出版日期:2013-03-26 发布日期:2013-03-26

Study on Thermal Conductivity of Polypropylene Composites Filled with Hybrid Particles Exfoliated Graphite

Hongwu Wu Xiaoqiang Xu Han Liu   

  • Received:2012-11-14 Revised:2012-12-24 Online:2013-03-26 Published:2013-03-26

摘要: 以不同粒径的膨胀石墨(EG)为填料,通过双辊混炼热压成型制备聚丙烯(PP)/ EG 导热复合材料,研究了EG填充量、粒径和不同粒径混杂填充对复合材料导热性能的影响。结果表明:随着EG填充量增加,复合材料的热导率提高。当填充量超过30 %时,热导率提升幅度增大,达到"渗流域值;当EG填充量为50 %时,复合材料的热导率达到1.791 W/(m·K);大粒径填料粒子提高复合材料热导率的能力优于小粒径粒子;大小粒径按合适比例混杂填充得到的复合材料热导率最高。

关键词: 膨胀石墨, 混杂填充, 聚丙烯, 导热性能, 复合材料

Abstract: Polypropylene (PP) composites filled with exfoliated graphite (EG) were prepared by roll mixing and hot press method. The effects of filler content, particle sizes, and hybrid filling on the thermal conductivity of the composites were investigated. The thermal conductivity of composites was improved with increasing EG filler contents. When the filling rate was over 30%, the thermal conductivity increased faster, achieving percolation threshold. When the filling rate was 50%, the thermal conductivity of composite material reached 1.791 W/(m·K). The large size filler particles were more beneficial to improve the thermal conductivity of composites than small size particles. If the mixture of hybrid particles was at a preferable mass ratio, the composites exhibited the highest thermal conductivity.

Key words: exfoliated graphite, hybrid filling, polypropylene, thermal conductivity, composite