中国塑料 ›› 2015, Vol. 29 ›› Issue (12): 23-28 .DOI: 10.19491/j.issn.1001-9278.2015.12.005

• 材料与性能 • 上一篇    下一篇

相容剂对PE-HD/回收纸塑铝复合材料性能的影响

郑赟1,黄宝铨1,陈庆华2,梁聪立1,肖荔人3   

  1. 1. 福建师范大学2. 福建师大环境科学与工程学院3. 福建师范大学材料科学与工程学院
  • 收稿日期:2015-06-02 修回日期:2015-09-22 出版日期:2015-12-26 发布日期:2015-12-26

Effect of Compatibilizers on Properties of PE-HD/Recycled Paper/Plastic/Aluminum Composites

  • Received:2015-06-02 Revised:2015-09-22 Online:2015-12-26 Published:2015-12-26

摘要: 分别以马来酸酐接枝聚乙烯(PE-g-MAH)、马来酸酐接枝乙烯辛烯共聚物(POE-g-MAH)、甲基丙烯酸甘油酯接枝乙烯辛烯共聚物(POE-g-GMA)为相容剂,采用熔融共混法制备了高密度聚乙烯(PE-HD)/回收纸塑铝包装粉末(r-PPA)复合材料。通过力学性能、流变性能、吸水率和扫描电子显微镜等分析,对3种相容剂的增容作用进行研究。结果表明,POE-g-GMA对复合材料力学性能影响最大,当添加量为6份时,复合材料的拉伸强度比未增容体系提高了32.9 %,脆断面出现韧性断裂的“拔丝”现象,且体系出现“类液类固”转变;PE-g-MAH对复合材料的吸水率影响最大,当添加量为10份时,复合材料的吸水率比未增容体系降低了54.2 %。

关键词: 高密度聚乙烯, 纸塑铝包装, 相容剂, 复合材料 , 力学性能 , 流变性能

Abstract: PE-g-MAH, POE-g-MAH, and POE-g-GMA were used as a compatibilizer separately in composites of PE-HD and recycled powder of paper/plastic/aluminum (r-PPA). The effect of the compatibilizers was characterized using mechanical property testing, rheological property, water absorption, and scanning electron microscope (SEM). It showed that POE-g-GMA had the greatest influence on the mechanical properties of composites. When 6 phr POE-g-GMA was introduced, the tensile strength was increased by 32.9 %. And the composite exhibited ductile fracture with fibrils observed on the brittle fracture surface. Furthermore, the system gave rise to a quasi solidliquid phase transition. PE-g-MAH had the greatest influence on the water adsorption of the composites. With 10 phr PE-g-MAH, the water adsorption was reduced by 54.2 %.

Key words: high density polyethylene, paper-plastic-aluminum package, compatilizer, composite , mechanical property , rheological behavior