中国塑料 ›› 2007, Vol. 21 ›› Issue (3): 49-52.

• 加工与应用 • 上一篇    下一篇

等规聚丙烯在振动注射中的力学性能和晶面择优取向

曾泰,朱记,文耀锋,张杰,申开智*
  

  1. 四川大学高分子科学与工程学院,高分子材料工程国家重点实验室,四川成都610065
  • 出版日期:2007-03-26 发布日期:2021-04-08
  • 基金资助:
    国家自然科学基金(50473053),国家基础研究专项经费12005CB623800),教育部留学回国人员科研自动基金联合资助

Mechanical Properties and Crystal Plane Orientation of IPP in Vibration Injection Molding

ZENG Tai,ZHU Ji,WEN Yao-feng,ZHANG Jie,SHEN Kai-zhi*   

  1. Department of Polymer Science&Engineering, State Key Laboratory of Polymer Material and Engineering, Sichuan University,Chengdu 610065,China
  • Online:2007-03-26 Published:2021-04-08

摘要: 采用自行研制的压力振动注射装置,在不同熔体温度、振动频率、振动压力下得到等规聚丙烯(IPP)振动注射试样。运用广角X射线衍射测试方法对样条表层晶体结构进行了表征。测试结果表明当熔体温度上升到230 °C时出现俘晶型,(3-IPP含量随振动频率和振动压力的卜升而增加。试样拉伸性能随振动压力增加而提高,引人振动会引起断裂伸长率的降低,但随振动频率的增加,断裂伸长率有上升趋势。运用极图表征IPPa晶型特征晶面取向情况,在相对的低频、低温、高压条件下,a(040)晶面法向有较好的流动方向择优取向;而在高频、高温、低压情况下,a( 040 )晶面法向有较好的法向方向择优取向。

关键词: 等规聚丙烯, 取向, 振动注射, 极图, 广一角X射线衍射

Abstract:

IPP injection samples are prepared by self-made vibration injection mold in different tempera- turepressure and vibrate frequency.WAXD methods were used to study the development and transi tions of different crvstalforms insurface laver. When melt temperature was 230C crvstal formed whose contentincreased with increasingvibration frequency and vibration pressure. Tensile strength in- creases with the vibration pressure.The elongation at break may be decreased by vibration of low fre- quency,however increased by high frequencyones.The orientation of a-crystal was characterized with polefigures. At low vibration frequency,low temperature and high vibration pressure, the normal of (040) plane of IPP orientated in Mdirection, while in the opposite condition in N-direction.

Key words: isotactic polypropylene;orientation;vibration injection; , pole figure;wide angle X ray diffraction

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