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›› 2023, Vol. 37 ›› Issue (10): 24-33.
马志蕊1,尹甜2,蒋志魁2,杨璠1,祝孟珂1,杨洋1,韩宇1,翁云宣3,张彩丽1
收稿日期:
2023-04-28
修回日期:
2023-05-23
出版日期:
2023-10-26
发布日期:
2023-10-26
基金资助:
Received:
2023-04-28
Revised:
2023-05-23
Online:
2023-10-26
Published:
2023-10-26
摘要: 综述了聚丁二酸丁二醇酯(PBS)及其共混物的制备及应用进展。目前国内外PBS的合成工艺主要有直接酯化法、酯交换法和扩链法。PBS的耐热性好、力学性能优良,是可完全生物降解的脂肪族聚酯,能从根本上解决塑料白色污染的重要材料之一。PBS与脆性可降解聚酯共混可以提高其韧性和生物降解性;通过与其他可再生资源如热塑性淀粉、木薯淀粉、开心果壳粉共混可以提高刚性和熔点,改善力学性能的同时降低成本;与少量无机填料如碳酸钙、二氧化硅等共混不仅可以降低PBS的价格还可以改善PBS的性能。PBS目前主要应用于包装材料、农林业用品、日用杂品、纺织业及医用制品中。PBS作为薄膜应用时其力学性能及气体阻隔性能是两项重要的指标,所以重点总结了对PBS复合膜的力学和阻隔性能的改善研究进展。最后对PBS未来的研究和发展方向进行了展望,指出PBS生产技术应该向综合性能高、成本低和绿色环保方向发展。
马志蕊 尹甜 蒋志魁 杨璠 祝孟珂 杨洋 韩宇 翁云宣 张彩丽. PBS及其复合膜的制备及应用研究进展[J]. , 2023, 37(10): 24-33.
[1] H. Thurber, G.W. Curtzwiler, Suitability of poly(butylene succinate) as a coating for paperboard convenience food packaging, International Journal of Biobased Plastics, 2 (2020) 1-12.[2] P. Liminana, D. Garcia-Sanoguera, L. Quiles-Carrillo, R. Balart, N. Montanes, Development and characterization of environmentally friendly composites from poly(butylene succinate) (PBS) and almond shell flour with different compatibilizers, Compos Part B-Eng, 144 (2018) 153-162.[3] P. Pan, Y. Inoue, Polymorphism and isomorphism in biodegradable polyesters, Prog Polym Sci, 34 (2009) 605-640.[4] Y.F. Shih, L.S. Chen, R.J. Jeng, Preparation and properties of biodegradable PBS/multi-walled carbon nanotube nanocomposites, Polymer, 49 (2008) 4602-4611.[5] J.B. Zeng, Y.D. Li, Q.Y. Zhu, K.K. Yang, X.L. Wang, Y.Z. Wang, A novel biodegradable multiblock poly(ester urethane) containing poly(L-lactic acid) and poly(butylene succinate) blocks, Polymer, 50 (2009) 1178-1186.[6] H. Suleyman, A. Albayrak, M. Bilici, E. Cadirci, Z. Halici, Different mechanisms in formation and prevention of indomethacin-induced gastric ulcers, Inflammation, 33 (2010) 224-234.[7] E. Rudnik, Compostable Polymer Materials, in: Handbook of Biopolymers and Biodegradable Plastics, 2013, pp. 189-211.[8] S.A. Rafiqah, A. Khalina, A.S. Harmaen, I.A. Tawakkal, K. Zaman, M. Asim, M.N. Nurrazi, C.H. Lee, A Review on Properties and Application of Bio-Based Poly(Butylene Succinate), Polymers (Basel), 13 (2021).[9] X.X. Zhou, Q. Dou, Preparation of Poly(Butylene Succinate)/Soy Protein Isolate Bio-Composites by Reactive Compatibilization with Peroxide and Acrylate, J Polym Environ, 30 (2022) 1847-1863.[10] M. Bautista, A.M. de Ilarduya, A. Alla, S. Munoz-Guerra, Poly(butylene succinate) Ionomers with Enhanced Hydrodegradability, Polymers, 7 (2015) 1232-1247.[11] M. Bautista, A.M. de Ilarduya, A. Alla, M. Vives, J. Morato, S. Munoz-Guerra, Cationic poly(butylene succinate) copolyesters, European Polymer Journal, 75 (2016) 329-342.[12] Y. Tokiwa, B.P. Calabia, C.U. Ugwu, S. Aiba, Biodegradability of plastics, Int J Mol Sci, 10 (2009) 3722-3742.[13] T. Messin, S. Marais, N. Follain, A. Guinault, V. Gaucher, N. Delpouve, C. Sollogoub, Biodegradable PLA/PBS multinanolayer membrane with enhanced barrier performances, Journal of Membrane Science, 598 (2020).[14] C. Kanemura, S. Nakashima, A. Hotta, Mechanical properties and chemical structures of biodegradable poly(butylene-succinate) for material reprocessing, Polym Degrad Stabil, 97 (2012) 972-980.[15] L. Yu, S.M. Ke, Y.H. Zhang, B. Shen, A.Z. Zhang, H.T. Huang, Dielectric relaxations of high-k poly(butylene succinate) based all-organic nanocomposite films for capacitor applications, J Mater Res, 26 (2011) 2493-2502.[16] N. Petchwattana, S. Covavisaruch, S. Wibooranawong, P. Naknaen, Antimicrobial food packaging prepared from poly(butylene succinate) and zinc oxide, Measurement, 93 (2016) 442-448.[17] J. Saeng-on, D. Aht-Ong, Compatibility of banana starch nanocrystals/poly(butylene succinate) bio-nanocomposite packaging films, Journal of Applied Polymer Science, 135 (2018).[18] P. Jariyasakoolroj, K. Makyarm, K. Klairasamee, A. Sane, L. Jarupan, Crystallization behavior analysis and reducing thermal shrinkage of poly(lactic acid) miscibilized with poly(butylene succinate) film for food packaging, Journal of Applied Polymer Science, (2023).[19] B. Xue, H. He, Z. Zhu, J. Li, Z. Huang, G. Wang, M. Chen, Z. Zhan, A Facile Fabrication of High Toughness Poly(lactic Acid) via Reactive Extrusion with Poly(butylene Succinate) and Ethylene-Methyl Acrylate-Glycidyl Methacrylate, Polymers (Basel), 10 (2018).[20] N. Mallegni, T.V. Phuong, M.B. Coltelli, P. Cinelli, A. Lazzeri, Poly(lactic acid) (PLA) Based Tear Resistant and Biodegradable Flexible Films by Blown Film Extrusion, Materials (Basel), 11 (2018).[21] Y. Deng, N.L. Thomas, Blending poly(butylene succinate) with poly(lactic acid): Ductility and phase inversion effects, European Polymer Journal, 71 (2015) 534-546.[22] W. Phetwarotai, H. Maneechot, E. Kalkornsurapranee, N. Phusunti, Thermal behaviors and characteristics of polylactide/poly(butylene succinate) blend films via reactive compatibilization and plasticization, Polymers for Advanced Technologies, 29 (2018) 2121-2133.[23] R. Supthanyakul, N. Kaabbuathong, S. Chirachanchai, Random poly(butylene succinate-co-lactic acid) as a multi-functional additive for miscibility, toughness, and clarity of PLA/PBS blends, Polymer, 105 (2016) 1-9.[24] E. Fortunati, D. Puglia, A. Iannoni, A. Terenzi, J.M. Kenny, L. Torre, Processing Conditions, Thermal and Mechanical Responses of Stretchable Poly (Lactic Acid)/Poly (Butylene Succinate) Films, Materials (Basel), 10 (2017).[25] V. Gigante, M.B. Coltelli, A. Vannozzi, L. Panariello, A. Fusco, L. Trombi, G. Donnarumma, S. Danti, A. Lazzeri, Flat Die Extruded Biocompatible Poly(Lactic Acid) (PLA)/Poly(Butylene Succinate) (PBS) Based Films, Polymers (Basel), 11 (2019).[26] M. Ma, L. Xu, K. Liu, S. Chen, H.W. He, Y.Q. Shi, X. Wang, Effect of triphenyl phosphite as a reactive compatibilizer on the properties of poly(L-lactic acid)/poly (butylene succinate) blends, Journal of Applied Polymer Science, 137 (2020).[27] B. Xue, H. He, Z. Zhu, J. Li, Z. Huang, G. Wang, M. Chen, Z. Zhan, A Facile Fabrication of High Toughness Poly(lactic Acid) via Reactive Extrusion with Poly(butylene Succinate) and Ethylene-Methyl Acrylate-Glycidyl Methacrylate, Polymers, 10 (2018).[28] M. Ma, L. Xu, K. Liu, S. Chen, H. He, Y. Shi, X. Wang, Effect of triphenyl phosphite as a reactive compatibilizer on the properties of poly(L‐lactic acid)/poly(butylene succinate) blends, J Appl Polym Sci, 137 (2019).[29] F. Wu, M. Misra, A.K. Mohanty, Novel tunable super-tough materials from biodegradable polymer blends: nano-structuring through reactive extrusion, RSC Adv, 9 (2019) 2836-2847.[30] P.M. Ma, D.G. Hristova-Bogaerds, P.J. Lemstra, Y. Zhang, S.F. Wang, Toughening of PHBV/PBS and PHB/PBS Blends via In situ Compatibilization Using Dicumyl Peroxide as a Free-Radical Grafting Initiator, Macromolecular Materials and Engineering, 297 (2012) 402-410.[31] B. Fahrngruber, M. Fortea-Verdejo, R. Wimmer, N. Mundigler, Starch/Poly(butylene succinate) Compatibilizers: Effect of Different Reaction-Approaches on the Properties of Thermoplastic Starch-Based Compostable Films, J Polym Environ, 28 (2020) 257-270.[32] R.S. Ayu, A. Khalina, A.S. Harmaen, K. Zaman, T. Isma, Q. Liu, R.A. Ilyas, C.H. Lee, Characterization Study of Empty Fruit Bunch (EFB) Fibers Reinforcement in Poly(Butylene) Succinate (PBS)/Starch/Glycerol Composite Sheet, Polymers (Basel), 12 (2020).[33] S. Rojas-Lema, J. Arevalo, J. Gomez-Caturla, D. Garcia-Garcia, S. Torres-Giner, Peroxide-Induced Synthesis of Maleic Anhydride-Grafted Poly(butylene succinate) and Its Compatibilizing Effect on Poly(butylene succinate)/Pistachio Shell Flour Composites, Molecules, 26 (2021).[34] M. Rasheed, M. Jawaid, B. Parveez, A. Hussain Bhat, S. Alamery, Morphology, Structural, Thermal, and Tensile Properties of Bamboo Microcrystalline Cellulose/Poly(Lactic Acid)/Poly(Butylene Succinate) Composites, Polymers (Basel), 13 (2021).[35] M. Rasheed, M. Jawaid, B. Parveez, Bamboo Fiber Based Cellulose Nanocrystals/Poly(Lactic Acid)/Poly(Butylene Succinate) Nanocomposites: Morphological, Mechanical and Thermal Properties, Polymers (Basel), 13 (2021).[36] J. Xu, P.H. Manepalli, L. Zhu, S. Narayan-Sarathy, S. Alavi, Morphological, barrier and mechanical properties of films from poly (butylene succinate) reinforced with nanocrystalline cellulose and chitin whiskers using melt extrusion, Journal of Polymer Research, 26 (2019).[37] Y. Zhang, S.M. Zhou, X.C. Fang, X. Zhou, J.Y. Wang, F.D. Bai, S.Z. Peng, Renewable and flexible UV-blocking film from poly(butylene succinate) and lignin, European Polymer Journal, 116 (2019) 265-274.[38] X. Zhou, T.Z. He, Y.K. Jiang, S.C. Chang, Y. Yu, X.C. Fang, Y. Zhang, A Novel Network-Structured Compatibilizer for Improving the Interfacial Behavior of PBS/Lignin, Acs Sustainable Chemistry & Engineering, 9 (2021) 8592-8602.[39] H.A. Saffian, M. Yamaguchi, H. Ariffin, K. Abdan, N.K. Kassim, S.H. Lee, C.H. Lee, A.R. Shafi, A. Humairah Alias, Thermal, Physical and Mechanical Properties of Poly(Butylene Succinate)/Kenaf Core Fibers Composites Reinforced with Esterified Lignin, Polymers (Basel), 13 (2021).[40] L. Xiong, Z. Tu, S. Zhang, X. Liu, X. Peng, Preparation of PBS and CaCO3 Composite Degradable Materials based on Melt Blending, IOP Conference Series: Materials Science and Engineering, 730 (2020).[41] T. Jamnongkan, A. Yosta, B. Thanesthakul, M. Sugimoto, T. Hara, Y. Takatsuka, R. Mongkholrattanasit, Effect of ZnO Nanoparticles on the Physical Properties of PLA/PBS Biocomposite Films, Materials Science Forum, 1033 (2021) 143-150.[42] L.C. Tan, Y. He, J.P. Qu, Structure and properties of Polylactide/Poly(butylene succinate)/Organically Modified Montmorillonite nanocomposites with high-efficiency intercalation and exfoliation effect manufactured via volume pulsating elongation flow, Polymer, 180 (2019).[43] N. Karakehya, Comparison of the effects of various reinforcements on the mechanical, morphological, thermal and surface properties of poly(butylene succinate), International Journal of Adhesion and Adhesives, 110 (2021).[44] C. Aversa, M. Barletta, A. Gisario, E. Pizzi, R. Prati, S. Vesco, Corotating twin-screw extrusion of poly(lactic acid) PLA/poly(butylene succinate) PBS/ micro-lamellar talc blends for extrusion blow molding of biobased bottles for alcoholic beverages, Journal of Applied Polymer Science, 138 (2021).[45] M. Ilsouk, M. Raihane, B. Rhouta, R.M. Meri, J. Zicans, J. Vecstaudza, M. Lahcini, The relationship of structure, thermal and water vapor permeability barrier properties of poly(butylene succinate)/organomodified beidellite clay bionanocomposites prepared by in situ polycondensation, RSC Adv, 10 (2020) 37314-37326.[46] L. Xie, H. Xu, B. Niu, X. Ji, J. Chen, Z.M. Li, B.S. Hsiao, G.J. Zhong, Unprecedented access to strong and ductile poly(lactic acid) by introducing In Situ Nanofibrillar Poly(butylene succinate) for green packaging, Biomacromolecules, 15 (2014) 4054-4064.[47] N. Bumbudsanpharoke, P. Wongphan, K. Promhuad, P. Leelaphiwat, N. Harnkarnsujarit, Morphology and permeability of bio-based poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS) and linear low-density polyethylene (LLDPE) blend films control shelf-life of packaged bread, Food Control, 132 (2022).[48] R. Sharma, S.M. Jafari, S. Sharma, Antimicrobial bio-nanocomposites and their potential applications in food packaging, Food Control, 112 (2020).[49] N. Aziman, L.K. Kian, M. Jawaid, M. Sanny, S. Alamery, Morphological, Structural, Thermal, Permeability, and Antimicrobial Activity of PBS and PBS/TPS Films Incorporated with Biomaster-Silver for Food Packaging Application, Polymers (Basel), 13 (2021).[50] A. Nanni, A. Ricci, A. Versari, M. Messori, Wine derived additives as poly(butylene succinate) (PBS) natural stabilizers for different degradative environments, Polym Degrad Stabil, 182 (2020).[51] L. Lopusiewicz, M. Zdanowicz, S. Macieja, K. Kowalczyk, A. Bartkowiak, Development and Characterization of Bioactive Poly(butylene-succinate) Films Modified with Quercetin for Food Packaging Applications, Polymers (Basel), 13 (2021).[52] V. Siracusa, P. Rocculi, S. Romani, M. Dalla Rosa, Biodegradable polymers for food packaging: a review, Trends Food Sci Tech, 19 (2008) 634-643.[53] K. Yamamoto-Tamura, Y.T. Hoshino, S. Tsuboi, C. Huang, A.W. Kishimoto-Mo, Y. Sameshima-Yamashita, H. Kitamoto, Fungal community dynamics during degradation of poly(butylene succinate-co-adipate) film in two cultivated soils in Japan, Biosci Biotechnol Biochem, 84 (2020) 1077-1087.[54] S. Bi, H. Pan, V. Barinelli, B. Eriksen, S. Ruiz, M.J. Sobkowicz, Biodegradable polyester coated mulch paper for controlled release of fertilizer, Journal of Cleaner Production, 294 (2021).[55] W.J. Liu, X.C. Ren, Study on the application of the narrow distribution and controlled molecular weight hindered amine lighter stabilizers in poly(butylene succinate), Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 56 (2019) 535-543. |
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