Research and Application Progress of Antioxidant Anti⁃migration Technology

doi:10.19491/j.issn.1001-9278.2020.12.016

Abstract

Abstract:

Antioxidants play an important role in preventing the oxidation of polyolefin materials. However， they are easy to migrate and volatilize， resulting in a reduction in antioxidation efficiency. Therefore， it is of great significance to improve the anti-migration of antioxidant. This paper introduced the recent research progress in antioxidant migration resistance through macro?molecularization， polymer encapsulation and inorganic particle immobilization. Furthermore， the existing problems and improvement methods of current antioxidant migration resistance technology were proposed， and the its development trend in future was prospected.

Key words: polyolefin, antioxidant, anti-migration, macro-molecularization

CLC Number:

TQ314

LI Chenyang, GONG Weiguang, MENG Xin, CAO Qiming, YAO Zhongyang. Research and Application Progress of Antioxidant Anti⁃migration Technology[J]. China Plastics, 2020, 34(12): 92-102.

Figures/Tables 17

Fig.1. Preparation of bifunctional antioxidant TAIC3S3Ph and molecular structure of CA1(revised according to reference[5])

Fig.2. Molecular structure of BM46TBPP

Fig.3. Preparation of EVOAP and POE?A[8]

Fig.4. Synthesis of norbornene polymerized antioxidant[10]

Fig.5. Encapsulated antioxidant nanosphere structure[11]

Fig.6. Structure of encapsulated phenolic antioxidant synthesized by electrospinning[11]

Fig.7. Preparation of AO?KH550?SiO2?TiO2[16]

Fig.8. Preparation of AO?MWCNT?B[19]

Fig.9. Chemical immobilization and physical adsorption process of AO?80[21]

Fig.10. Preparation of PPSQ

Fig.11. Relationship between oxidation induction temperature and hydrolysis time of PP samples

Fig.12. Immobilization process of HNTs?4010NA[23]

Fig.13. Test results of migration resistance and mechanical property of SBR#4 and SBR#6 after aging[24]

Fig.14. Migration process of RD in rubber[25]

Fig.15. Molecular structure of intercalation antioxidant

Fig.16. Preparation of AO?OM?MMt[33]

Fig.17. Mechanism of antioxidant release by Hoffman elimination reaction[31]

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