Research progress in marine antifouling coatings based on fluorosilicone polymers

doi:10.19491/j.issn.1001-9278.2024.10.010

Abstract

Abstract:

The severe pollution of marine organisms has greatly restricted the development and utilization of marine resources. At present the surface coating with marine anti⁃fouling coatings is one of the most widely used， effective， and economical methods to avoid marine organism pollution. The marine anti⁃fouling coatings based on fluorosilicone polymers are a class of non⁃stick coatings with great development prospects. This article introduced four common methods for synthesizing fluorosilicone polymers， including anionic ring⁃opening polymerization， atom transfer radical polymerization， hydrosilylation reaction， and thiol⁃ene click reaction. The research progress in the modification of fluorosilicone polymers was reviewed from the perspectives of organic chain segment modification and nanomaterial modification. Furthermore， the challenges and future development directions for the marine anti⁃fouling coatings based on fluorosilicone polymers were proposed.

Key words: fluorosilicone polymer, marine antifouling coating, polyurethane, epoxide resin, acrylic series chemicals, nanometer material

CLC Number:

TQ325

LI Xi, WANG Xin, QI Wen, QI Dingwen. Research progress in marine antifouling coatings based on fluorosilicone polymers[J]. China Plastics, 2024, 38(10): 55-59.

Figures/Tables 5

Fig.1. Polysiloxane structural formula

Fig.2. Schematic diagram of synthesis of fluoropropyl methylsiloxane⁃dimethylsiloxane containing methacryloxy by anionic ring⁃opening polymerization［11］

Fig.3. Schematic diagram of synthesis of fluoro⁃silicon polymer grafted modified nano⁃silica by ATRP［12］

Fig.4. Schematic diagram of synthesis of single⁃ended silanized side chain fluoroalkyl polyether by hydrosilylation［13］

Fig.5. Schematic diagram of FS⁃SS synthesis by mercaptan ⁃ ene click method［14］

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