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© 《China Plastics》
© 《China Plastics》
China Plastics ›› 2022, Vol. 36 ›› Issue (11): 24-29.DOI: 10.19491/j.issn.1001-9278.2022.11.004
• Materials and Properties • Previous Articles Next Articles
WANG Fang(), LI Yan, GUO Xintao, DOU Peng
Received:
2022-07-25
Online:
2022-11-26
Published:
2022-11-25
CLC Number:
WANG Fang, LI Yan, GUO Xintao, DOU Peng. Synthesis and properties of ternary polysulfone copolymer containing bisphenol fluorene[J]. China Plastics, 2022, 36(11): 24-29.
样品编号 | DCS含量/ mol | BPA含量/ mol | BHPF含量/ mol | BHPF摩尔 分数/ % |
---|---|---|---|---|
PSFF⁃0 | 0.05 | 0.050 | 0 | 0 |
PSFF⁃20 | 0.05 | 0.040 | 0.010 | 20 |
PSFF⁃30 | 0.05 | 0.035 | 0.015 | 30 |
PSFF⁃50 | 0.05 | 0.025 | 0.025 | 50 |
PSFF⁃70 | 0.05 | 0.015 | 0.035 | 70 |
PSFF⁃80 | 0.05 | 0.010 | 0.040 | 80 |
PSFF⁃100 | 0.05 | 0 | 0.050 | 100 |
样品编号 | DCS含量/ mol | BPA含量/ mol | BHPF含量/ mol | BHPF摩尔 分数/ % |
---|---|---|---|---|
PSFF⁃0 | 0.05 | 0.050 | 0 | 0 |
PSFF⁃20 | 0.05 | 0.040 | 0.010 | 20 |
PSFF⁃30 | 0.05 | 0.035 | 0.015 | 30 |
PSFF⁃50 | 0.05 | 0.025 | 0.025 | 50 |
PSFF⁃70 | 0.05 | 0.015 | 0.035 | 70 |
PSFF⁃80 | 0.05 | 0.010 | 0.040 | 80 |
PSFF⁃100 | 0.05 | 0 | 0.050 | 100 |
Na2CO3/K2CO3 摩尔比 | Mn/ kg·mol-1 | Mw/ kg·mol-1 | Mw/Mn | Tg/℃ |
---|---|---|---|---|
1/0 | 3.325 | 4.457 | 1.340 | 147 |
1/5 | 4.920 | 6.647 | 1.351 | 199 |
1/10 | 8.621 | 13.670 | 1.586 | 239 |
0/1 | 21.390 | 38.260 | 1.789 | 252 |
Na2CO3/K2CO3 摩尔比 | Mn/ kg·mol-1 | Mw/ kg·mol-1 | Mw/Mn | Tg/℃ |
---|---|---|---|---|
1/0 | 3.325 | 4.457 | 1.340 | 147 |
1/5 | 4.920 | 6.647 | 1.351 | 199 |
1/10 | 8.621 | 13.670 | 1.586 | 239 |
0/1 | 21.390 | 38.260 | 1.789 | 252 |
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