中国塑料

中国塑料 ›› 2008, Vol. 22 ›› Issue (05): 74-77 .DOI: 10.19491/j.issn.1001-9278.2008.05.016

• 助剂 • 上一篇    下一篇

10,10'-(5H, 5'H)-双螺磷杂吖嗪氯化物在ABS中的阻燃性能研究

崔金海，师兆忠，姬学亮   

  1. 开封大学化学工程学院，河南 开封475001
  • 收稿日期:2007-12-30 修回日期:1900-01-01 出版日期:2008-05-25 发布日期:2008-05-25

Research on Flame Retardance of 10，10'-(5H，5H)-SPI-obiphenophosphazinium Chloride in ABS

CUI Jin-hai，SHI Zhao-Zhong，JI Xue-Liang   

  1. College of Chemical Fnginecring,Kaifeng University, Kaifeng 475001 ,China
  • Received:2007-12-30 Revised:1900-01-01 Online:2008-05-25 Published:2008-05-25
  • Contact: CUI Jin-hai

摘要： 介绍了10,10'-(5H, 5'H)-双螺磷杂吖嗪氯化物作为阻燃剂的理沦依据、制备方法，采用均匀试验设计方法探讨10,10'-(5H, 5'H)-双螺磷杂吖嗪氯化物在丙烯腈-丁二烯-苯乙烯共聚物(ABS)中作为阻燃剂的阻燃特性，用SPSS统计软件对其力学性能影响因素和氧指数进行了回归分析。结果表明，ABS/110,10'-(5H, 5'H)一双螺磷杂吖嗪氯化物/氢氧化铝质量比为100 /22 /18时，复合材料的拉伸强度为32.80 MPa，冲山强度为24.7KJ/m2缺口冲击强度为9.02KJ/m2数为26.1%；水平燃烧等级达到I级;垂直燃烧等级达到FV-0级。实验表明10,10'-(5H, 5'H)-双螺磷杂吖嗪氯化物具有理想的阻燃特性，综合性能较好。

关键词: 丙烯腈-丁二烯-苯乙烯共聚物, 10, 10'-(5H, 5'H)-双螺磷杂吖嗪氯化物, 均匀试验设计, 阻燃特性

Abstract: A flame retardant，10，10'-(5H，5H)-Spirobiphenophosphazinium chloride was prepared，its effects on the flame retardance and mechanical properties of ABS/Al(OH)3 composites were explored via regressive analysis of the data from a uniform design experiments using SPSS software. When the weight ratio of ABS, 10，10'-(5H，5H)-spirobiphcnophosphazinium, and Al(OH)3 in the composite was 100 /22 /18，excellent comprehensive properties were obtained.The notched，non-notched impact strengths, and tensile strength were 9.02KJ/m2 2.80 MPa, respectively. The oxygen index was 26. 1，horizontal firing ranked I，and vertical firing ranked FV-0.

Key words: acrylonitrile-butadiene-styrene copolymer, 10, 10'-(5H, 5H)spirobiphc-nophosphazinium, uniform design, flame retardancy

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