中国塑料 ›› 2009, Vol. 23 ›› Issue (11): 89-93 .DOI: 10.19491/j.issn.1001-9278.2009.11.018

• 塑料与环境 • 上一篇    下一篇

PPR的官能化及其对回收PET瓶片的增韧研究

赵庆 王益龙 王 真   

  1. 大连理工大学 大连理工大学
  • 收稿日期:2009-07-13 修回日期:2009-09-07 出版日期:2009-11-26 发布日期:2009-11-26

Study on Functionalization of PPR and Its Toughening Effect on Recycled PET Flakes

Zhao Qing   

  • Received:2009-07-13 Revised:2009-09-07 Online:2009-11-26 Published:2009-11-26

摘要: 利用接枝型反应挤出机研究了无规共聚聚丙烯(PPR)接枝马来酸酐反应的最佳配方,并利用缩聚型反应挤出机研究了其接枝产物(PPR-g-MAH)的接枝率大小、用量对回收饮料瓶片(r-PET)增韧作用的影响。结果表明,PPR-g-MAH生产的最佳配方为:马来酸酐3 %,DCP引发剂0.03 %;选择接枝率为4.2 mmolMAH/100 g的PPR-g-MAH、用量为10 %时,r-PET/ PPR-g-MAH共混物的力学性能最好,可以作为工程塑料使用;扫描电镜分析表明,官能化的PPR明显比纯PPR提高了分散相的分散效果。

关键词: 回收饮料瓶片, 无规共聚聚丙烯, 聚对苯二甲酸乙二醇酯, 反应挤出, 增韧

Abstract: Maleic anhydride (MA) was grafted onto polypropylene random copolymer (PPR) with a grafting reactive extruder, and the grafted product (PPR-g-MAH) was used as a toughening agent for recycled PET flakes (r-PET) in a condensation reactive extruder. The optimal recipe for PPR-g-MAH was obtained as: 3 % of MAH, 0.03 % of initiator DCP. The mechanical properties of r-PET/PPR-g-MAH alloy were optimal when grafting rate was 4.2 mmol/100g and PPR-g-MAH content was 10 %. SEM showed that with MA grafted, PPR achieved a finer dispersion in r-PET compared with neat PPR.

Key words: recycled bottle flakes, random polypropylene, poly(ethyleneglycol terephthalate), reactive extrusion, toughening

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