中国塑料 ›› 2010, Vol. 24 ›› Issue (05): 43-47 .DOI: 10.19491/j.issn.1001-9278.2010.05.010

• 材料与性能 • 上一篇    下一篇

牙科根管桩钉用纤维/树脂可塑性复合材料的优化制备研究

胡江 何惠明 刘玉红 郑亚萍   

  1. 吉林医药学院附属医院
  • 收稿日期:2010-01-27 修回日期:1900-01-01 出版日期:2010-05-26 发布日期:2010-05-26

Optimized Preparation of Fiber/Resin Thermoplastics Composites for Dental Endodontic Posts

Jiang HU Huiming HE Yuhong LIU Yaping ZHENG   

  • Received:2010-01-27 Revised:1900-01-01 Online:2010-05-26 Published:2010-05-26
  • Contact: Jiang HU

摘要: 以聚双酚A二甲基丙烯酸缩水甘油酯/聚甲基丙烯酸甲酯共混体系为基体,以玻璃纤维为增强相,采用优化的纤维浸润-热预聚-拉挤成型等工艺,制备出了具有可塑性的光固化型玻璃纤维/树脂复合材料。通过玻璃化转变温度考察了共混体系的相容性,用扫描电子显微镜观察了共混体系断口的微观形貌,用三点弯曲试验考察了共混体系和复合材料的力学性能。结果表明,在聚双酚A二甲基丙烯酸缩水甘油酯/聚甲基丙烯酸甲酯=80/20的共混体系中浸入74.1 %(质量分数,下同)的玻璃纤维,在80 ℃下热聚合2 h,再经1.0 cm/min的匀速拉挤成型,最后通过可见光固化60 s,此工艺下制备出的复合材料的弯曲强度达到648.01 MPa,弯曲模量达到33.12 GPa,更接近于牙本质。

关键词: 根管桩, 玻璃纤维, 复合材料, 力学性能

Abstract: A new type of fiber-reinforced thermoplastic composite for dental endodontic post was prepared, in which a blend of poly(bisphenol A glycidyl dimethacrylate)/poly(methyl methacrylate) (PBGD/PMMA) was used as the matrix and glass fiber as reinforcer. The composite was characterized using glass transition temperature determination, SEM observation, and three-point bending test. The optimal preparation process was as follows: 74.1 wt % of glass fiber was impregnated with a mixture of monomers (BGD/MMA=80/20w), after a pre-polymerization at 80℃ for 2 h, the prepreg was pultruded at 1.0 cm/min and subsequently photopolymerized for 60 s. Thus obtained composite gave rise to a bending strength of 648.01 MPa and a bending modulus of 33.12 GPa, which was close to those of dentin.

Key words: endodontic post, glass fiber, composite, mechanical property

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