中国塑料 ›› 2010, Vol. 24 ›› Issue (08): 23-27 .DOI: 10.19491/j.issn.1001-9278.2010.08.006

• 材料与性能 • 上一篇    下一篇

酚醛树脂/蒙脱土纳米复合材料的制备及其性能研究

吴江涛 齐暑华 李春华 莫军连 李美玲 尚磊   

  1. 西北工业大学理学院化学系
  • 收稿日期:2010-01-18 修回日期:2010-03-10 出版日期:2010-08-26 发布日期:2010-08-26

Preparation and Properties of Phenolic Resin/Montmorillonite Nano-composites

  

  • Received:2010-01-18 Revised:2010-03-10 Online:2010-08-26 Published:2010-08-26

摘要: 利用原位聚合法制备了酚醛树脂/蒙脱土(PF/MMT)纳米复合材料,通过对其力学性能和电学性能的研究发现,当MMT含量为5 %(质量分数,下同)时,复合材料的综合性能最好,拉伸强度是未改性PF的2.33倍,体积电阻率提高了4个数量级,热失重速率最大时所对应的温度提高了15.24 ℃,线烧蚀率为未改性PF的80 %。并通过扫描电子显微镜对复合材料烧蚀面的观察,建立了耐烧蚀复合材料的烧蚀模型。

关键词: 酚醛树脂, 蒙脱土, 复合材料, 原位聚合法, 力学性能, 电性能, 烧蚀性能

Abstract: Phenolic resin/montmorillonite(PF/MMT) nano-composites were prepared via in-situ polymerization in this paper. Through the research on mechanical and electrical properties of PF/MMT composites, it was found that the overall performance was the best when the content of montmorillonite was 5 wt %, the tensile strength of the PF/MMT nano-composite was 2.33 times that of neat phenolic resin, and the volume resistivity also increased four orders of magnitude. Meanwhile, the temperature at the maximum thermal weight loss rate increased 15.24 ℃, the line ablation rate was 80 % of neat phenolic resin. An ablation model of the anti-ablative composites was established through the observation of surface ablation of the composites by SEM.

Key words: phenolic resin, montmorillonite, composite, in-situ polymerization, mechanical property, electrical property, ablation performance