中国塑料 ›› 2010, Vol. 24 ›› Issue (09): 49-52 .DOI: 10.19491/j.issn.1001-9278.2010.09.012

• 材料与性能 • 上一篇    下一篇

炭黑填充PE-HD/EVA/PE-LD导电发泡复合材料的阻温特性

李继新;王立岩;李素君;张木;吴全才   

  1. 沈阳工业大学石油化工学院
  • 收稿日期:2010-07-07 修回日期:2010-07-27 出版日期:2010-09-26 发布日期:2010-09-26

Resistivity Temperature Behavior of Acetylene Carbon Black Filled PE-HD/EVA/PE-LD Conductive Foamed Composites

  • Received:2010-07-07 Revised:2010-07-27 Online:2010-09-26 Published:2010-09-26

摘要: 以高密度聚乙烯(PE-HD)为聚合物基体材料,乙烯-乙酸乙烯酯(EVA)为增韧剂,低密度聚乙烯(PE-LD)为增塑剂,乙炔炭黑(ACET)为导电填料,偶氮二甲酰胺(AC)为发泡剂,过氧化二异丙苯(DCP)为交联剂制备了PE-HD/EVA/PE-LD /ACET导电发泡复合材料。结果表明,PE-HD/EVA/PE-LD=50/30/20(质量比,下同),ACET填加量为35 % (质量分数,下同)、发泡剂AC的添加量为4 %、交联剂DCP填加量为0.5 %时,制备的导电泡沫具有比较理想的闭孔泡孔结构。经过升温电阻测试,发现PE-HD/EVA/PE-LD/ACET导电发泡复合材料具有良好的开关特性,呈现明显的正温度系数特性(PTC)特性;AC发泡剂用量为4 %时,PTC效应最强。

关键词: 乙炔炭黑, 低密度聚乙烯, 乙烯-乙酸乙烯酯, 高密度聚乙烯, 发泡, 正温度系数特性, 发泡复合材料

Abstract:

PE-HD/EVA/PE-LD/ACET conductive foamed composites were prepared using acetylene carbon black (ACET) as a conductive filler, azobisformamide (AC) as a foamer, and dicumyl peroxide(DCP) as a cross-linker. Closed cell structure was obtained when PE-HD/EVA/PE-LD is 50:30:20(w/w/w),and acetylene carbon black, azobisformamide, and dicumyl peroxide content were 35, 4, and 0.5 wt %, respectively. The prepared conductive foam composites had good switching characteristics, and displayed positive temperature coefficient (PTC) effect, which was the strongest when the contents of AC was 4 wt %.

Key words: Composition materials, Carbon black, High-density polyethylene, Foam, Positive temperature coefficient(PTC) effect

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