中国塑料 ›› 2012, Vol. 26 ›› Issue (04): 86-91 .DOI: 10.19491/j.issn.1001-9278.2012.04.017

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纳米氧化锌填充PBS复合材料性能的研究

刘文广 张秀成 李红媛 刘滨 李春凡   

  1. 东北林业大学理学院 东北林业大学理学院 东北林业大学理学院
  • 收稿日期:2011-12-14 修回日期:2012-02-13 出版日期:2012-04-26 发布日期:2012-04-26

Effect of Nano-ZnO on Properties of Poly(butylene succinate)

Wenguang LIU Xiucheng ZHANG Hongyuan LI Bin LIU Chunfan LI   

  • Received:2011-12-14 Revised:2012-02-13 Online:2012-04-26 Published:2012-04-26
  • Contact: Xiucheng ZHANG

摘要: 采用硅烷偶联剂(KH-550)对纳米氧化锌进行表面改性,通过熔融共混法制备了聚丁二酸丁二醇酯(PBS)/纳米氧化锌复合材料,利用扫描电子显微镜、热重分析仪、差示扫描量热仪等对复合材料的力学性能、热性能和非等温结晶性能进行研究分析,并通过Ozawa-Flynn-Wall方法分析了复合材料的热降解行为。结果表明,纳米氧化锌能够提高PBS的拉伸强度和弯曲强度,但却降低了其冲击强度;改性后的纳米氧化锌可以提高其与PBS的界面相容性,并提高其在PBS基体中的分散性能,不同程度地提高了复合材料的力学性能;纳米氧化锌提高了PBS的结晶速率,降低了其热解反应活化能。

关键词: 复合材料, 纳米氧化锌, 聚丁二酸丁二醇酯, 力学性能

Abstract: Nano-ZnO was surface modified with KH-550, with which poly(butylene succinate)(PBS)/nano-ZnO composites were prepared via melt blending. The mechanical, thermal, and non-isothermal crystallization behavior of the composites were studied using SEM, TG, and DSC, respectively. The thermal degradation behavior was analyzed using Ozawa-Flynn-Wall method. It showed that the tensile and flexural strengths of PBS/ nano-ZnO composites increased with adding nano-ZnO, but impact strength decreased. Surface modification could improve the interfacial compatibility between nano-ZnO and PBS matrix and the dispersion of nano-ZnO in PBS matrix. Thus the mechanic properties of composites were enhanced. The crystallization rate of PBS was increased when nano-ZnO was added, and the thermal degradation activation energy was decreased.

Key words: composite, nano-zinc oxide, poly(butylene succinate), mechanical property