中国塑料 ›› 2012, Vol. 26 ›› Issue (05): 1-6 .DOI: 10.19491/j.issn.1001-9278.2012.05.001

• 综述 •    下一篇

聚丁二酸乙二醇酯合成的研究进展

马楷 刘绍英 王公应   

  1. 中国科学院成都有机化学研究所 中国科学院成都有机化学研究所 中国科学院成都有机化学研究所
  • 收稿日期:2011-12-19 修回日期:2012-02-20 出版日期:2012-05-26 发布日期:2012-05-26

Research Progress in Synthesis of Poly(ethylene glycol succinate)

Ma Kai Shaoying Liu Gongying Wang   

  • Received:2011-12-19 Revised:2012-02-20 Online:2012-05-26 Published:2012-05-26
  • Contact: Ma Kai

摘要: 综述了直接酯化聚合法、丁二酸酐开环聚合法、酯交换聚合法、耦合反应法合成聚丁二酸乙二醇酯(PES)的国内外研究进展,着重介绍了丁二酸和乙二醇酯化聚合法合成PES的催化剂和工艺的研究现状,并展望了PES及其合成工艺的发展前景。

关键词: 聚丁二酸乙二醇酯, 合成, 直接酯化聚合法, 丁二酸酐开环聚合法, 酯交换聚合法, 耦合反应法, 催化剂, 工艺

Abstract: Four kinds of methods for the synthesis of poly(ethylene glycol succinate)(PES) were reviewed, including direct esterification, ring-opening polymerization, transesterification polymerization, and coupling reaction. The technology of direct esterification and the involved catalysts were emphatically introduced. Moreover, the development of PES synthesis was forecasted.

Key words: poly(ethylene glycol succinate), synthesis, direct esterification, ring-opening polymerization, transesterification polymerization, coupling reaction, catalyst, process