中国塑料 ›› 2013, Vol. 27 ›› Issue (07): 62-67.DOI: 10.19491/j.issn.1001-9278.2013.07.012

• 加工与应用 • 上一篇    下一篇

γ射线辐照交联改性超高相对分子质量聚乙烯的研究

薛平,何振强,戚晓芸   

  1. 北京化工大学
  • 收稿日期:2013-03-25 修回日期:2013-05-01 出版日期:2013-07-26 发布日期:2013-07-26

Research on ultra-high molecular weight polyethylene crosslinked by gamma irradiation

  • Received:2013-03-25 Revised:2013-05-01 Online:2013-07-26 Published:2013-07-26

摘要: 采用单螺杆挤出机制备了PE-UHMW板材,并用不同剂量的γ射线对其进行进行辐照交联,分析不同辐照剂量和辐照后处理对其力学性能、耐热性能、摩擦磨损性能等的影响。结果表明,在一定的辐照剂量下,γ射线辐照交联可以提高PE-UHMW的凝胶率、熔点、结晶度、拉伸强度、表面硬度、热变形温度和耐磨性能。当辐照剂量为150 kGy时,PE-UHMW的热变形温度提高了近40 ℃。但辐照交联降低了PE-UHMW的塑性,使材料的拉伸断裂伸长率降低。重新熔融后处理可以进一步提高材料的凝胶率,改善其塑性,但材料的熔点、结晶度、表面硬度、拉伸强度有所降低。

Abstract: In this paper, PE-UHMW sheets were extruded by single screw extruder and crosslinked by different gamma irradiation does thereafter. Effect of gamma irradiation does and treatment on properties PE-UHMW composites was studied. With a proper does of gamma irradiation, the gel content、melting point、crystallinity、surface hardness、tensile strength、heat distortion temperature and wear resistance of UHMWPE could be improved. Heat distortion temperature of UHMWPE was increased by 40 ℃ when the gamma irradiation does reached 150 kGy. But gamma irradiation crosslinking reduced its toughness. The tensile elongation at break decreased. Remlting could further increase the gel content and enhanced its toughness, but reducing the melting point, crystallinity, surface hardness, tensile strength.

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