中国塑料 ›› 2013, Vol. 27 ›› Issue (08): 81-85.DOI: 10.19491/j.issn.1001-9278.2013.08.016

• 助剂 • 上一篇    下一篇

十二烷基苯磺酸钠和聚乙烯醇改性氢氧化镁阻燃剂的实验研究

白俊红,刘有智*,申红艳   

  1. 中北大学山西省超重力化工工程技术研究中心,山西太原030051
  • 收稿日期:2013-03-25 修回日期:2013-06-20 出版日期:2013-08-26 发布日期:2020-11-16

Experiment study on flame retardant of magnesium hydroxide modified by sodium dodecyl benzene sulfonate or polyvinyl alcohol

BAI Junhong,LIU Youzhi*,SHEN Yanhong   

  1. Research Center of Shanxi Province for High Gravity Chemical Engineering and Technology, North University of China,Taiyuan 030051,China

  • Received:2013-03-25 Revised:2013-06-20 Online:2013-08-26 Published:2020-11-16

摘要: 氢氧化镁因为同时具有阻燃、消烟和填充等功能,已成为人们日益关注的一种无机环保型阻燃材料。实验分别将十二烷基苯磺酸钠和聚乙烯醇作为改性剂,对氢氧化镁进行在线改性,且针对改性前后的氢氧化镁进行了沉降性能、过滤性能、活化度、吸油值和黏度等性能的对比。实验结果表明:十二烷基苯磺酸钠的最佳添加量为2.5%,此时氢氧化镁浆液的沉降速率达到1.111×10-4m/s,比未改性时增加了近11倍,滤饼比阻减小到21.835×10-10m/Kg,活化度增加到97.62%,吸油值减小到28.5mL/100gMg(OH)2,黏度也减小到原来的1/2左右;聚乙烯醇的最佳添加量为1.5%,此时氢氧化镁浆液的沉降速率达到5.208×10-4m/s,比未改性时增加了近50倍,滤饼比阻减小到20.779×10-10m/Kg,活化度增加到97.73%,吸油值减小到25ml/100gMg(OH)2,黏度也减小到原来的1/2左右。

关键词: 氢氧化镁, 表面改性, 十二烷基苯磺酸钠, 聚乙烯醇

Abstract: Magnesium hydroxide retardant,smoke and fill at the same time,has become a growing concern inorganic environment-friendly flame retardant materials. Research of online modified was made on magnesium hydroxide flame retardant by sodium dodecyl benzene sulfonate or polyvinyl alcohol.Then contrast settling propertise、filter performance、activation、oil absorption value and viscosity before and after modification. The stirring speed under the conditions of 200-300rpm,the experimental results show that:the best optimal amount of sodium dodecyl benzene sulfonate was 2.5%,the magnesium hydroxide magnitude sedimentation rate achieve 1.111×10-4m/s,increase 11 times nearly,cake specific resistance was reduced to 21.835×10-10m/Kg, activation grade reach to97.62%,oil absorption value decreased to 28.5mL/100gMg(OH)2, viscosity reduced about 1/2 of unmodified;the best optimal amount of polyvinyl alcohol was 1.5%,the magnesium hydroxide magnitude sedimentation rate achieve 5.208×10-4m/s ,increase 50 times nearly,cake specific resistance was reduced to 20.779×10-10m/Kg,activation grade reach to97.73%,oil absorption value decreased to25mL/100gMg(OH)2 and viscosity reduced about 1/2 of unmodified.

Key words: magnesium hydroxide, surface modification, sodium dodecyl benzene sulfonate, polyvinyl alcohol

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