中国塑料 ›› 2013, Vol. 27 ›› Issue (10): 6-11 .DOI: 10.19491/j.issn.1001-9278.2013.10.002

• 综述 • 上一篇    下一篇

苯并噁嗪分子内杂化树脂的研究进展

毛柯 颜红侠 贾园 李婷婷   

  1. 西北工业大学 陕西省西安市西北工业大学理学院化学系 西北工业大学理学院
  • 收稿日期:2013-06-09 修回日期:1900-01-01 出版日期:2013-10-26 发布日期:2013-10-26

Research Progress of Intramolecular Hybrid Resin of Benzoxazine

Li Ting Ting   

  • Received:2013-06-09 Revised:1900-01-01 Online:2013-10-26 Published:2013-10-26

摘要: 综述了近年来利用分子设计方法,简述了通过在苯并噁嗪单体中引入磷、硼、溴、硅和硫等杂原子以提高苯并噁嗪树脂的耐热性能及力学性能的研究进展,并指出了其未来的研究方向,即合成工艺设计及单体结构设计,同时还展望了其应用前景。

关键词: 苯并噁嗪, 开环聚合, 杂化树脂, 研究进展

Abstract: This paper reviews recent research progress of intramolecular hybrid benzoxazine resin. The intramolecular hybrid method included inclusion of heteroatoms such as phosphorus, boron, silicon, bromine, and sulphur into benzoxazine monomer to improve the heat resistance and mechanical properties of benzoxazine resin. The design of structure of the monomer and synthesis process was also discussed. The further development of benzoxazine resin was also forecast.

Key words: benzoxazine, ringopening polymerization, hybrid resin, research progress