中国塑料 ›› 2014, Vol. 28 ›› Issue (02): 25-30.DOI: 10.19491/j.issn.1001-9278.2014.02.004

• 材料与性能 • 上一篇    下一篇

PBTA/TPS共混物的结构、性能和断裂行为

李旭娟 钟淦基 冉蓉 李忠明 丁建萍 姜天伟 宋玉玲   

  • 收稿日期:2013-09-11 修回日期:2013-12-03 出版日期:2014-02-26 发布日期:2014-02-26

Morphology and properties of biodegradable thermoplastic starch/poly(butylene adipate-co-terephthalate) composites

  

  • Received:2013-09-11 Revised:2013-12-03 Online:2014-02-26 Published:2014-02-26

摘要: 将热塑性淀粉(TPS)与聚(对苯二甲酸丁二醇酯-己二酸丁二醇酯)(PBAT)挤出共混并注塑成型,制备了可完全生物降解的TPS/PBAT复合材料制品。采用扫描电子显微镜研究了注塑复合材料的层次结构与微观形态,测试了不同组分复合材料的性能和应力应变行为。结果表明:TPS在PBAT中呈皮芯结构分布,随含量增加逐渐由芯层向皮层分布。当含量为45%时,芯层到皮层形成均匀的以纤维为主的分散相形态,提高了复合材料的力学性能。加入TPS后会改变复合材料的形变行为,由类似半结晶聚合物的应力应变行为转变为屈服-冷拉行为。

关键词: 聚(对苯二甲酸丁二醇酯一己二酸丁二醇酯), 热塑性淀粉, 原位成纤

Abstract: A series of fully biodegradable composites were prepared by melt blending thermoplastic starch(TPS) and poly(butylene adipate-co-terephthalate) (PBAT) using a twin screw extruder.The microstructure and fracture behavior of the composites were studied with scanning electron microscopy(SEM) before and after drawing, the properties of the composites with different compositions were tested.The results indicated that the skin-core structure formed after injection, TPS was inclined to disperse in the core and then distributed from core to skin with increasing content of TPS. It was obviously that the continuous fiber morphology from core to skin can improve the mechanical properties of composites, the addition of TPS also can change the stress-strain behavior of composites, of which took a transition from semicrystalline polymer stress-strain behavior to typical yield cold-drawing behavior.

Key words: poly(butylene adipatecoterephthalate), thermoplastic starch, fibrillar morphology