中国塑料 ›› 2014, Vol. 28 ›› Issue (12): 50-59.DOI: 10.19491/j.issn.1001-9278.2014.12.012

• 材料与性能 • 上一篇    下一篇

超临界CO2辅助挤出制备PP/POE共混物微观形态与性能

陈士宏1,佟昱霖2,马秀清3,王奎升   

  1. 1. 北京化工大学
    2. 北京工商大学材料与机械工程学院
    3. 北京化工大学机电工程学院
  • 收稿日期:2020-11-19 修回日期:2014-07-28 出版日期:2014-12-26 发布日期:2014-12-26

Morphology and Properties of PP/POE Blends Prepared by Supercritical C02一aided Extrusion

  • Received:2020-11-19 Revised:2014-07-28 Online:2014-12-26 Published:2014-12-26
  • Contact: CHEN CHEN ShihongShihong E-mail:xxx@plaschina.com.cn

摘要: 采用带有超临界CO2注人装置的双阶挤出机组制备了聚丙烯/乙烯一辛烯共聚物(PP/POE)(100/10)共混物。采用扫描电子显微镜观察了PP/POE共混物脆断面的微观形态,利用ImagePro Plus软件定量分析了弹性体POE粒子在PP基体中分散的平均粒径和粒径分布,通过差示扫描量热仪和偏光显微镜考察了PP/POE共混物的结晶过程。结果表明,当超临界CO2注人量为2. 5份(样品PP2. 5)时,弹性体POE粒子在PP基体中的分散粒径最小,粒径分布最窄;其中最小平均粒径为0.34 μm,粒径分布为1. 44;样品PP2. 5的结晶度最高,为53. 57%,且具有最细小致密的晶体形态。

Abstract: Polypropylene/Ethylene-octene copolymer blends(PP/POE = 100/10)were prepared using a two-stage extruder with the aid of supercritical carbon dioxide(sc-CO2).The morphology of PP/POE blends was characterized by scanning electron microscope, and the size distribution of POE in PP based on SEM images was carried out quantitatively using a computerized image analyzer with Image-Pro Plus software. n differential scanning calorimeter was used to study the crystallization and melting behaviors of the samples,and the crystal morphology of PP/POE blends was observed by polarized optical microscopy equipped with a hot stage. The results showed that PP2. 5 sample, in which POE elastomer droplets were uniformly dispersed,had minimum average diameter(0. 34 μm) and size distribution(1. 44)of POE elastomer domains. PP2. 5 sample also had the highest degree of crystallinity (53. 57%),and the smallest size of crystallites in all of the samples.

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