中国塑料 ›› 2015, Vol. 29 ›› Issue (03): 95-99 .DOI: 10.19491/j.issn.1001-9278.2015.03.017

• 加工与应用 • 上一篇    下一篇

聚乙烯醇/淀粉纳米晶复合膜的制备及表征

卞其波,田华峰,王娅茹,刘茜,项爱民   

  1. 北京工商大学
  • 收稿日期:2015-02-02 修回日期:2015-02-09 出版日期:2015-03-26 发布日期:2015-03-26

Preparation and Characterization of Poly(vinyl alcohol)/Starch Nanocrystals Composite Films

  • Received:2015-02-02 Revised:2015-02-09 Online:2015-03-26 Published:2015-03-26

摘要: 利用蜡质玉米淀粉通过硫酸酸解制备淀粉纳米晶(SN),并采用溶液流延法制备聚乙烯醇(PVA)/SN复合膜,研究SN对复合膜结构和性能的影响。结果表明,制备的SN样品为盘状颗粒,平均直径为30~60 nm;随着SN含量的增加,PVA/SN复合膜的力学性能和阻隔性能均呈现先增后减的变化;在SN含量为10 %时,复合膜的拉伸和阻隔性能最好,拉伸强度由纯PVA膜的47 MPa提高至54 MPa,气体透过系数相对于纯PVA膜也降低了70 %。

关键词: 聚乙烯醇, 淀粉纳米晶, 力学性能 , 阻隔性能

Abstract: Starch nanocrystals (SN) was prepared by sulfuric acid hydrolysis with waxy maize starch as the starting material and polyvinyl alcohol (PVA)/SN nanocomposite films were prepared by solution casting method. The effect of SN on the structure and properties of the PVA/SN composite films was studied. The characterization results showed that SN was composed of nano particles as disk shape with an average diameter around 30~60 nm. With the increase of SN in the composite films, both mechanical properties and barrier performance firstly increased and then decreased. When the content of SN increased to 10 %, the tensile strength of the composite film reached 54 MPa from 47 MPa of neat PVA film. In addition, the gas permeability of the composite films also decreased 70 % compared with the neat film.

Key words: polyvinyl alcohol, starch nanocrystals, mechanical property , barrier property