中国塑料 ›› 2015, Vol. 29 ›› Issue (04): 82-87 .DOI: 10.19491/j.issn.1001-9278.2015.04.015

• 加工与应用 • 上一篇    下一篇

强韧化PBT/PC共混物的制备与性能

曾晓强1,孟东伟1,曹长林1,陈昌禧2,陈华泽2,陈庆华3   

  1. 1. 福建师范大学2. 福建湄洲湾氯碱工业有限公司3. 福建师大环境科学与工程学院
  • 收稿日期:2014-11-03 修回日期:2015-01-28 出版日期:2015-04-26 发布日期:2015-04-26

Preparation and Properties of Strengthened and Toughened PBT/PC Blends

  • Received:2014-11-03 Revised:2015-01-28 Online:2015-04-26 Published:2015-04-26

摘要: 采用自制的甲基丙烯酸缩水甘油酯熔融接枝丙烯腈丁二烯苯乙烯三元聚合物\[ABS-g-(GMA-co-St),AGS]为改性剂,对聚对苯二甲酸丁二醇酯(PBT)/聚碳酸酯(PC)(80/20)共混物进行改性研究。通过扫描电子显微镜、差示扫描量热仪、力学性能和流变性能测试研究了改性后共混物的性能。结果表明,随着AGS含量的增加,共混物中两相间的界面黏结增强; AGS对PBT/PC共混物具有强韧化的作用,与未添加AGS的PBT/PC共混物相比,当AGS含量为10份时,共混物的缺口冲击强度和拉伸强度分别提高了49.8 %和17.4 %;AGS的加入提高了共混物的界面强度和相容性;添加AGS能够提高共混物的结晶峰温度,起到促进晶粒生长的作用。

关键词: 聚对苯二甲酸丁二醇酯, 聚碳酸酯, 共混物, 增强, 增韧, 力学性能, 流变行为, 结晶性能

Abstract: Glycidyl methacylate functionalized acrylonitrilebutadienestyrene copolymer\[ABS-g-(GMA-co-St), AGS] was prepared by melting grafting and was used to modify poly(butylene terephthalate)/polycarbonate (PBT/PC=80/20) blends. SEM showed that the interfacial adhesion between PBT and PC was improved with increasing AGS content. The addition of 10 wt % of AGS caused 49.8 % and 17.4 % increments in notched impact strength and tensile strength of the PBT/PC blends, respectively, the interfacial bonding strength and miscibility of the blends were also enhanced. In addition, DSC test indicated that the incorporation of AGS increased the crystallization peak temperature and spherulite growth rate of the blends.

Key words: poly (butyl glycol terephthalate), polycarbonate, blend, reinforcement, toughening, mechanical property, rheological behavior, crystallization property