中国塑料 ›› 2016, Vol. 30 ›› Issue (01): 56-60 .DOI: 10.19491/j.issn.1001-9278.2016.01.010

• 材料与性能 • 上一篇    下一篇

基于超临界CO2间歇法制备超轻TPU颗粒的研究

张艳娜1,秦柳2,张聪3,陈承涛3,杨卫民4   

  1. 1. 青岛科技大学2. 北京化工大学3. 宁波格林美孚新材料科技有限公司4. 北京化工大学英蓝实验室
  • 收稿日期:2015-08-03 修回日期:2015-09-28 出版日期:2016-01-26 发布日期:2016-01-26

Preparation of Ultra-light Micro Foam TPU Particles by Supercritical CO2 Batch Method

  • Received:2015-08-03 Revised:2015-09-28 Online:2016-01-26 Published:2016-01-26

摘要: 采用超临界流体间歇式微发泡技术制备了超轻热塑性聚氨酯弹性体(TPU)颗粒,利用扫描电子显微镜等研究了发泡温度、饱和时间及饱和压力对制备超轻TPU颗粒密度和性能的影响。结果表明,发泡温度和饱和压力是影响颗粒泡孔结构分布和粒料性能的主要因素;当饱和压力为11 MPa、发泡温度为145 ℃时,所得的超轻TPU颗粒密度较小、粒径较大,其内部泡孔数量较多,泡孔结构分布均匀。

关键词: 超临界流体, TPU, 发泡温度, 饱和压力, 密度

Abstract: This article introduced the preparation of ultra-light TPU granules through batch foaming by supercritical fluid. The effect of foaming temperature, saturation time, and saturation pressure on the density and performance of TPU granules was studied. It showed that the foaming temperature and pressure constituted the main factors influencing the particle cell structure distribution. When the saturation pressure and temperature were 11 MPa and 145 ℃, respectively,the foamed TPU granules possessed low density, big size,large and uniform porosity.

Key words: supercutical fluid, TPU, foaming temperature, saturation pressure, density