中国塑料 ›› 2016, Vol. 30 ›› Issue (08): 17-22 .DOI: 10.19491/j.issn.1001-9278.2016.08.003

• 材料与性能 • 上一篇    下一篇

SBS/PE-LD的强化交联与形状记忆效应研究

白克铭,朱光明,王燕,沈学霖,杨鹏飞   

  1. 西北工业大学应用化学系
  • 收稿日期:2016-04-25 修回日期:2016-06-20 出版日期:2016-08-26 发布日期:2016-08-26

Shape Memory Effects of SBS/PELD Blends Crosslinked by Dicumyl Peroxide and Multifunctional Monomers

  • Received:2016-04-25 Revised:2016-06-20 Online:2016-08-26 Published:2016-08-26

摘要: 用苯乙烯丁二烯共聚物(SBS)与低密度聚乙烯(PE-LD)共混,采用过氧化二异丙苯(DCP)作为引发剂,3种不同的多官能团单体作为强化交联剂,使共混物发生强化交联形成网状结构,对多官能团单体的强化交联作用进行了分析,测试了交联共混物的拉伸强度与断裂伸长率,探讨了交联共混物的形状记忆效应。结果表明,多官能团单体的加入能够显著提高SBS/PE-LD交联共混物的交联程度,交联SBS/PE-LD共混物具有优异的形状记忆性能,形状固定率和形状回复率均可达100 %。

关键词: 低密度聚乙烯, 苯乙烯-丁二烯共聚物, 强化交联, 力学性能, 形状记忆效应

Abstract: A series of shape memory materials was fabricated by blending styrene butadiene copolymer (SBS) with low density polyethylene (PE-LD) and crosslinked by dicumyl peroxide (DCP) in the presence of multifunctional monomers. The degree of crosslinking,tensile strength,and elongation at break of the crosslinked blends were investigated. The results indicated that multifunctional monomers played an enhancing role in the chemical crosslinking of SBS/PE-LD blends and the crosslinked SBS/PE-LD blends exhibited an excellent shape memory behavior,the shape fixed ratio and the shape recovery ratio of the crosslinked SBS/PE-LD blends could be 100 %. With increasing content of multifunctional monomers,the degree of crosslinking of the blends increased.

Key words: low density polyethylene, styrene butadiene copolymer, enhanced crosslinking, mechanical property, shape memory effect