中国塑料 ›› 2016, Vol. 30 ›› Issue (09): 82-87 .DOI: 10.19491/j.issn.1001-9278.2016.09.015

• 塑料与环境 • 上一篇    下一篇

PP-g-MAH用量对废旧聚烯烃/木粉复合材料性能的影响

董金虎   

  1. 陕西理工学院
  • 收稿日期:2016-06-23 修回日期:2016-08-05 出版日期:2016-09-26 发布日期:2016-09-26

Influence of PP-g-MAH Content on the Properties of Recycled Polyolefin/Wood Flour Composites

  • Received:2016-06-23 Revised:2016-08-05 Online:2016-09-26 Published:2016-09-26

摘要: 以木粉和废旧聚烯烃塑料为原材料制备了废旧聚烯烃/木粉复合材料,讨论了不同助剂对复合材料加工性能的影响,并进一步探讨了马来酸酐接枝聚丙烯(PP-g-MAH)用量对复合材料的加工性能、力学性能以及微观结构的影响。结果表明,在复合材料中同时添加PP-g-MAH和乙烯-醋酸乙烯脂(EVA),其加工性能明显优于只添加EVA的复合材料;EVA用量为2 %时,PP-g-MAH用量高于9 %时,复合材料具有较低的剪切扭矩和熔融能耗;PP-g-MAH用量低于12 %时,复合材料的综合力学性能较好;而PP-g-MAH用量为9%~12%时,废旧聚烯烃形成了较为完善的连续相结构,此时复合材料的加工性能和力学性能均较好。

关键词: 马来酸酐接枝聚丙烯, 废旧聚烯烃, 木粉, 复合材料, 加工性能, 力学性能

Abstract: Waste polyolefin / wood flour composites were prepared, and the influence of PP-g-MAH and other additives on the mechanical properties and microstructure of the composites was studied. The processing property of the composites containing both PP-g-MAH and EVA was significantly better than that containing EVA alone. When the EVA content was 2% and the PP-g-MAH content was higher than 9%, the composite material had a lower shear torque. When the PP-g-MAH was 9~12%, the recycled polyolefin formed a continuous phase structure, the processing and mechanical properties of the composites were excellent.

Key words: polypropylene grafted maleic anhydride, recycled polyolefin, wood flour, composite, processing ability, mechanical property