中国塑料 ›› 2016, Vol. 30 ›› Issue (12): 41-46 .DOI: 10.19491/j.issn.1001-9278.2016.12.008

• 材料与性能 • 上一篇    下一篇

使用转矩流变仪评价硬聚氯乙烯的凝胶化度

王文治1,关龙龙1,梁小娟2,李均立2,李染1   

  1. 1. 顾地科技股份有限公司2. 佛山顾地塑胶有限公司
  • 收稿日期:2016-08-04 修回日期:2016-09-26 出版日期:2016-12-26 发布日期:2016-12-26

Evaluation of Gelation Degree of Unplasticized Poly(vinyl chloride) by Torque Rheometer

  • Received:2016-08-04 Revised:2016-09-26 Online:2016-12-26 Published:2016-12-26

摘要: 对硬聚氯乙烯(PVC-U) 转矩流变曲线的分析和实验验证发现, PVC-U的凝胶化度越大,其转矩流变曲线的最小扭矩越高,最大扭矩与最小扭矩的差值越小,据此提出了使用转矩流变仪评价PVC-U凝胶化度的方法。

关键词: 聚氯乙烯, 凝胶化度, 转矩流变仪

Abstract: The rheological characteristics of unplasticized poly(vinyl chloride)(PVC-U)was evaluated by a torque rheometer. The resulting rheological torque curves indicated that PVC-U achieved a higher minimum torque with its gelation degree getting greater, thus, the difference between its maximum and minimum torques became smaller. On the basis of this relationship, an evaluation method was proposed for estimating the gelation degree of PVC-U.

Key words: poly(vinyl chloride), gelation degree, torque rheometer