中国塑料 ›› 2016, Vol. 30 ›› Issue (12): 91-96 .DOI: 10.19491/j.issn.1001-9278.2016.12.017

• 塑料与环境 • 上一篇    下一篇

废旧聚甲醛/改性竹纤维复合材料的力学性能研究

沈玉婷,伍敏萍,屈建强,周武艺,董先明   

  1. 华南农业大学
  • 收稿日期:2016-08-04 修回日期:2016-09-10 出版日期:2016-12-26 发布日期:2016-12-26

Study on Mechanical Properties of Recycled Polyoxymethylene/Modified Bamboo Fiber Composites

  • Received:2016-08-04 Revised:2016-09-10 Online:2016-12-26 Published:2016-12-26
  • Contact: DONG Xian-Ming

摘要: 采用碱(NaOH)、硅烷偶联剂(KH560)、异氰酸酯(IPDI)等不同处理方法对废旧聚甲醛/竹纤维(POM/BF)复合材料的界面进行调控,研究了竹纤维改性方法和竹纤维含量对复合材料力学性能的影响。结果表明,NaOH+IPDI和NaOH+KH560能够实现对复合材料界面的调控,利用NaOH+2 %IPDI对BF进行处理后,POM/BF复合材料[BF为20 %(质量分数,下同)]的弯曲强度增加了13.38 %,拉伸强度为50.36 MPa;利用NaOH+5 %KH560对BF进行调控处理后,POM/BF复合材料的弯曲强度增加了12.61 %,拉伸强度为46.87 MPa;NaOH+2 %IPDI对BF的处理具有更好的效果,BF含量为20 %时复合材料的力学性能最佳。

关键词: 竹纤维, 聚甲醛, 复合材料, 界面调控, 力学性能

Abstract: An interfacial control for bamboo fibers (BF) with recycled polyoxymethylene (rePOM) was conducted by using NaOH, alkali and silanecoupling agent, alkali and isocyanate, respectively. Effects of modification method and BF content on mechanical properties of the re-POM/BF composites were investigated. The results indicated that this interfacial control could be well performed by the mixtures of NaOH with silanecoupling agent and with isocyanate. An increase of 13.38 % in flexure strength along with tensile strength of 50.36 MPa was achieved for composites containing 20 wt % of BF modified by the mixture of NaOH with 2 wt % isocyanate. On the other hand, the composite obtained an increase in flexure strength by 12.61 % as well as tensile strength of 46.87 MPa. It was concluded that the mixture of alkali with 2 wt % isocyanate could generate a much better modification effect on BF, and the composite containing 20 wt % BF achieved the optimum mechanical properties.

Key words: bamboo fiber, polyoxymethylene, composite, interface control, mechanical property