中国塑料 ›› 2017, Vol. 31 ›› Issue (03): 40-45 .DOI: 10.19491/j.issn.1001-9278.2017.03.008

• 材料与性能 • 上一篇    下一篇

预处理对汉麻杆芯粉填充天然橡胶/丁苯橡胶性能的影响

王杰1,周洪福2,张建春3   

  1. 1. 运城学院应用化学系2. 北京工商大学材料与机械工程学院3. 总后军需装备所汉麻材料研究中心
  • 收稿日期:2016-10-24 修回日期:2016-12-05 出版日期:2017-03-26 发布日期:2017-03-26

Effect of Pretreatment on Properties of Hemp-hurd-powder-filled Natural Rubber/Tyrene-butadiene Rubber Composites

  • Received:2016-10-24 Revised:2016-12-05 Online:2017-03-26 Published:2017-03-26
  • Contact: Jie WANG

摘要: 以废旧的生物质材料汉麻杆芯粉(HP)为填料,通过不同的预处理改性,研究了其对所填充的天然橡胶/丁苯橡胶(NR/SBR)复合材料的硫化性能、微观形态结构、拉伸力学性能、动态力学性能以及耐磨性和耐疲劳性能的影响。结果表明,具有较小尺寸的HP对橡胶的硫化性能影响不大,填充后的硫化胶拉伸断裂强度从3.5 MPa增加到10.6 MPa,撕裂强度从22.9 kN/m增加到32.9 kN/m,但耐磨性和耐疲劳性能下降;改性处理明显改善了填充效果,乳液改性处理方法优于偶联剂改性处理方法。

关键词: 汉麻杆芯粉, 天然橡胶, 丁苯橡胶, 偶联剂改性, 乳液改性, 力学性能

Abstract: Hemp hurd powders (HP) were used as a type of waste biobased fillers for the preparation of natural rubber (NR)/styrene-butadiene Rubber (SBR) composites, and the surfaces of HP were pretreated by means of several different methods before being used. The effect of pretreatment on curing characteristics, morphological structure, tensile properties,dynamic mechanical properties, abrasion resistance and fatigue resistance of NR/SBR composites was investigated. The results indicated that smallsized HP had litter influence on curing characteristics. Compared with pristine NR/SBR composites, the presence of HP led to an increase in tensile strength from 3.5 MPa to 10.6 MPa and an increase in tear strength from 22.9 kN/m to 32.9 kN/m. However, HP exhibited a negative effect on the abrasion and cyclic fatigue life of the composites. The pretreatments played an important role in improving physical properties of NR/SBR composites, and furthermore, latex coagulation treatment was a better method than the coupling agent one.

Key words: hemp hurd powder, natural rubber, styrene-butadiene rubber, coupling agent treatment, latex coagulation treatment, mechanical property