中国塑料 ›› 2017, Vol. 31 ›› Issue (4): 24-29 .DOI: 10.19491/j.issn.1001-9278.2017.04.005

• 材料与性能 • 上一篇    下一篇

碳纤维增强聚丙烯复合材料的制备及性能研究

陈姗1,唐梓健1,李彦涛2,杨东勇1,徐建彩1,陈征宇1,王欣怡1,杨丽庭1   

  1. 1. 华南师范大学化学与环境学院2. 华南师范大学
  • 收稿日期:2016-12-23 修回日期:2017-01-05 出版日期:2017-04-26 发布日期:2017-04-26

Study on Preparation and Properties of Carbon Fiber-reinforced Polypropylene

  • Received:2016-12-23 Revised:2017-01-05 Online:2017-04-26 Published:2017-04-26

摘要: 选取3种不同规格的短切碳纤维(CF),分别通过挤出注塑的方法制备了不同CF填充量的聚丙烯/碳纤维复合材料(PP/CF),并对其力学性能、熔体流动性能、硬度和热稳定性等性能进行了表征研究。结果表明,相比长度为0.5 mm的CF和粒径为74 μm的CF粉,长度为7 mm的CF更能显著提高复合材料的拉伸强度、弯曲强度和冲击强度,但会降低材料的断裂伸长率;3种CF的加入都会降低复合材料的熔体流动速率,且填充量越大,降低效果越明显;3种CF都能提高材料的硬度,填充量越大,硬度越大;另外,CF能改善材料的热稳定性,CF对复合材料的熔融温度影响不明显,但能提高其结晶温度。

关键词: 聚丙烯, 碳纤维, 复合材料, 规格, 填充量

Abstract: Polypropylene (PP)-based composites reinforced by three different carbon fiber (CF) were prepared by melt extrusion and their mechanical properties, melt fluidity, hardness and thermal stability were investigated. The results indicated that the composites achieved much higher tensile strength, flexural strength and impact toughness when using the CF with a length of 7 mm compared with the other two types of CF. However, the incorporation of these three types of CF reduced the melt fluidity of the composites. The higher the content of CF, the lower the melt fluidity. However, higher CF content resulted in greater hardness. The thermal stability was also improved with the addition of CF. Moreover, the presence of CF did not affect the melting temperature of the composite but improved their crystallization temperatures.

Key words: polypropylene, carbon fiber, composite, specification, fiber content